Cobalt versus osmium: control of both trans and cis selectivity in construction of the EFG rings of pectenotoxin 4
Catalytic oxidative cyclisation reactions have been employed for the synthesis of the E and F rings of the complex natural product target pectenotoxin 4. The choice of metal catalyst (cobalt or osmium based) allowed for the formation of THF rings with either trans or cis stereoselectivity. Fragment...
| Main Authors: | , , , , , , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
Wiley
2017
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