Mesoporous silica-supported zirconocene catalysts for highly isotactic polypropylene.
A new bis(indenyl)zirconocene bearing a pendant Si-Cl anchor has been grafted onto MCM-41, SBA-15, MCM-48 and a disordered mesoporous silica for the polymerisation of ethylene and propylene, producing polymers with very high molecular weights, low polydispersities and, in the case of polypropylene,...
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
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2004
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| _version_ | 1826296417200635904 |
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| author | Miller, C O'Hare, D |
| author_facet | Miller, C O'Hare, D |
| author_sort | Miller, C |
| collection | OXFORD |
| description | A new bis(indenyl)zirconocene bearing a pendant Si-Cl anchor has been grafted onto MCM-41, SBA-15, MCM-48 and a disordered mesoporous silica for the polymerisation of ethylene and propylene, producing polymers with very high molecular weights, low polydispersities and, in the case of polypropylene, higher levels of isotacticity than obtainable with analogous homogeneous systems. |
| first_indexed | 2024-03-07T04:16:00Z |
| format | Journal article |
| id | oxford-uuid:c970fc18-f0f4-4479-b30d-5aa83a519eaf |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T04:16:00Z |
| publishDate | 2004 |
| record_format | dspace |
| spelling | oxford-uuid:c970fc18-f0f4-4479-b30d-5aa83a519eaf2022-03-27T06:59:06ZMesoporous silica-supported zirconocene catalysts for highly isotactic polypropylene.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:c970fc18-f0f4-4479-b30d-5aa83a519eafEnglishSymplectic Elements at Oxford2004Miller, CO'Hare, DA new bis(indenyl)zirconocene bearing a pendant Si-Cl anchor has been grafted onto MCM-41, SBA-15, MCM-48 and a disordered mesoporous silica for the polymerisation of ethylene and propylene, producing polymers with very high molecular weights, low polydispersities and, in the case of polypropylene, higher levels of isotacticity than obtainable with analogous homogeneous systems. |
| spellingShingle | Miller, C O'Hare, D Mesoporous silica-supported zirconocene catalysts for highly isotactic polypropylene. |
| title | Mesoporous silica-supported zirconocene catalysts for highly isotactic polypropylene. |
| title_full | Mesoporous silica-supported zirconocene catalysts for highly isotactic polypropylene. |
| title_fullStr | Mesoporous silica-supported zirconocene catalysts for highly isotactic polypropylene. |
| title_full_unstemmed | Mesoporous silica-supported zirconocene catalysts for highly isotactic polypropylene. |
| title_short | Mesoporous silica-supported zirconocene catalysts for highly isotactic polypropylene. |
| title_sort | mesoporous silica supported zirconocene catalysts for highly isotactic polypropylene |
| work_keys_str_mv | AT millerc mesoporoussilicasupportedzirconocenecatalystsforhighlyisotacticpolypropylene AT ohared mesoporoussilicasupportedzirconocenecatalystsforhighlyisotacticpolypropylene |