INFRARED BOUND TO QUASIBOUND VIBRATION-ROTATION SPECTRUM OF HEH+ AND ITS ISOTOPES
The positions and widths of all the bound and rotationally quasibound levels of the ground states of 4HeH-, 4HeD′-3HeH- and 3HeD′ have been calculated using an adiabatic potential. From these theoretical data the positions of bound to quasibound vibration-rotation transitions lying in the range of t...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
1983
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| Summary: | The positions and widths of all the bound and rotationally quasibound levels of the ground states of 4HeH-, 4HeD′-3HeH- and 3HeD′ have been calculated using an adiabatic potential. From these theoretical data the positions of bound to quasibound vibration-rotation transitions lying in the range of the carbon dioxide laser 0880 to 1090 cm 1 have been predicted. Infrared predissociation spectroscopy of Doppler-tuned ion beams has been used to determine the positions and widths of many of the resonances. There is excellent agreement between the theoretical predictions and the experimental measurements. © 1983. |
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