Reactions and applications of titanium imido complexes.
This Account highlights aspects of the reactions and applications of titanium imido complexes. Over the past decade in particular, the Ti=NR linkage has been shown to couple stoichiometrically with a variety of unsaturated substrates including CO(2), carbodiimides, isocyanates, isocyanides, acetonit...
Main Authors: | , |
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Format: | Journal article |
Language: | English |
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2005
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_version_ | 1797094600261763072 |
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author | Hazari, N Mountford, P |
author_facet | Hazari, N Mountford, P |
author_sort | Hazari, N |
collection | OXFORD |
description | This Account highlights aspects of the reactions and applications of titanium imido complexes. Over the past decade in particular, the Ti=NR linkage has been shown to couple stoichiometrically with a variety of unsaturated substrates including CO(2), carbodiimides, isocyanates, isocyanides, acetonitrile, phosphaalkynes, alkynes, alkenes, and allenes. Especially recently, there has been much interest in using titanium imides as catalysts for hydroamination and olefin polymerization. The advances in these areas are also reviewed. |
first_indexed | 2024-03-07T04:16:14Z |
format | Journal article |
id | oxford-uuid:c9855f20-a975-4562-8d3d-bc8ace62cdc3 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-07T04:16:14Z |
publishDate | 2005 |
record_format | dspace |
spelling | oxford-uuid:c9855f20-a975-4562-8d3d-bc8ace62cdc32022-03-27T06:59:40ZReactions and applications of titanium imido complexes.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:c9855f20-a975-4562-8d3d-bc8ace62cdc3EnglishSymplectic Elements at Oxford2005Hazari, NMountford, PThis Account highlights aspects of the reactions and applications of titanium imido complexes. Over the past decade in particular, the Ti=NR linkage has been shown to couple stoichiometrically with a variety of unsaturated substrates including CO(2), carbodiimides, isocyanates, isocyanides, acetonitrile, phosphaalkynes, alkynes, alkenes, and allenes. Especially recently, there has been much interest in using titanium imides as catalysts for hydroamination and olefin polymerization. The advances in these areas are also reviewed. |
spellingShingle | Hazari, N Mountford, P Reactions and applications of titanium imido complexes. |
title | Reactions and applications of titanium imido complexes. |
title_full | Reactions and applications of titanium imido complexes. |
title_fullStr | Reactions and applications of titanium imido complexes. |
title_full_unstemmed | Reactions and applications of titanium imido complexes. |
title_short | Reactions and applications of titanium imido complexes. |
title_sort | reactions and applications of titanium imido complexes |
work_keys_str_mv | AT hazarin reactionsandapplicationsoftitaniumimidocomplexes AT mountfordp reactionsandapplicationsoftitaniumimidocomplexes |