Reactions and applications of titanium imido complexes.

This Account highlights aspects of the reactions and applications of titanium imido complexes. Over the past decade in particular, the Ti=NR linkage has been shown to couple stoichiometrically with a variety of unsaturated substrates including CO(2), carbodiimides, isocyanates, isocyanides, acetonit...

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Main Authors: Hazari, N, Mountford, P
Format: Journal article
Language:English
Published: 2005
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author Hazari, N
Mountford, P
author_facet Hazari, N
Mountford, P
author_sort Hazari, N
collection OXFORD
description This Account highlights aspects of the reactions and applications of titanium imido complexes. Over the past decade in particular, the Ti=NR linkage has been shown to couple stoichiometrically with a variety of unsaturated substrates including CO(2), carbodiimides, isocyanates, isocyanides, acetonitrile, phosphaalkynes, alkynes, alkenes, and allenes. Especially recently, there has been much interest in using titanium imides as catalysts for hydroamination and olefin polymerization. The advances in these areas are also reviewed.
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spelling oxford-uuid:c9855f20-a975-4562-8d3d-bc8ace62cdc32022-03-27T06:59:40ZReactions and applications of titanium imido complexes.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:c9855f20-a975-4562-8d3d-bc8ace62cdc3EnglishSymplectic Elements at Oxford2005Hazari, NMountford, PThis Account highlights aspects of the reactions and applications of titanium imido complexes. Over the past decade in particular, the Ti=NR linkage has been shown to couple stoichiometrically with a variety of unsaturated substrates including CO(2), carbodiimides, isocyanates, isocyanides, acetonitrile, phosphaalkynes, alkynes, alkenes, and allenes. Especially recently, there has been much interest in using titanium imides as catalysts for hydroamination and olefin polymerization. The advances in these areas are also reviewed.
spellingShingle Hazari, N
Mountford, P
Reactions and applications of titanium imido complexes.
title Reactions and applications of titanium imido complexes.
title_full Reactions and applications of titanium imido complexes.
title_fullStr Reactions and applications of titanium imido complexes.
title_full_unstemmed Reactions and applications of titanium imido complexes.
title_short Reactions and applications of titanium imido complexes.
title_sort reactions and applications of titanium imido complexes
work_keys_str_mv AT hazarin reactionsandapplicationsoftitaniumimidocomplexes
AT mountfordp reactionsandapplicationsoftitaniumimidocomplexes