Direct observation of anharmonic coupling in the time domain with femtosecond stimulated Raman scattering.
Off-resonant impulsive Raman excitation is used to initiate nonstationary nuclear motion in low-frequency vibrational modes of deuterio-chloroform. Femtosecond time-resolved stimulated Raman probing of the high-frequency C-D stretch reveals additional vibrational sidebands that arise as a result of...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2006
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