Redox-dependent metal-metal bonding in trinuclear metal chains: probing the transition from covalent bonding to exchange coupling
The synthesis and physical properties of two new cationic tri-metallic chains, [(PEt3 )3 RuCl3 M'Cl3 Ru(PEt3 )3 ]1+ , M'=Rh and Ir are reported. These are isostructural with a previously reported 17-electron all-ruthenium analogue, but replacing a d5 RuIII ion in the central position with...
| Main Authors: | , , , , , |
|---|---|
| 格式: | Journal article |
| 语言: | English |
| 出版: |
Wiley
2017
|