A rhodium(III) complex of the linear diborazine H3B·NMe2BH2·NMe2H: an intermediate in the dehydrocoupling of H3B·NMe2H.

A rhodium(III) complex of the linear diborazine H3B·NMe2BH2·NMe2H: an intermediate in the dehydrocoupling of H3B·NMe2H.

The solid-state structure of the rhodium complex (dimethylamine-dimethylaminoborane-borane-κ(2)H,H')dihydridobis(triisopropylphosphane-κP)rhodium(III) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate, [RhH(2)(C(4)H(18)B(2)N(2))(C(9)H(21)P)(2)](C(32)H(12)BF(24)), is reported. The complex contains...

Descripción completa

Detalles Bibliográficos
Autores principales:	Chaplin, AB, Weller, A
Formato:	Journal article
Lenguaje:	English
Publicado:	2011

Ejemplares similares

[Ir(PCy3)2(H)2(H2B-NMe2)]+ as a latent source of aminoborane: probing the role of metal in the dehydrocoupling of H3B⋅NMe2H and retrodimerisation of [H2BNMe2]2.
por: Stevens, C, et al.
Publicado: (2011)

Development of a generic mechanism for the dehydrocoupling of amine-boranes: a stoichiometric, catalytic, and kinetic study of H3B·NMe2H using the [Rh(PCy3)2]+ fragment.
por: Sewell, L, et al.
Publicado: (2012)

Catching the first oligomerization event in the catalytic formation of polyaminoboranes: H3B·NMeHBH2·NMeH2 bound to iridium.
por: Johnson, H, et al.
Publicado: (2011)

Dehydropolymerization of H³B·NMeH² using a [Rh(DPEphos)]⁺ catalyst: the promoting effect of NMeH²
por: Adams, G, et al.
Publicado: (2019)

Crystal structure of [(trimethylsilyl)-bis(dimethylaminoboryl)amino]- (trimethylsilylamino)-(dimethylamino)-borane, [(Me3Si)NH(BNMe2)]N[B(NMe2)2](SiMe3)
por: Jäschke T., et al.
Publicado: (2002-12-01)

Crystal structure of [(trimethylsilyl)-bis(dimethylaminoboryl)amino]- (trimethylsilylamino)-(dimethylamino)-borane, [(Me3Si)NH(BNMe2)]N[B(NMe2)2](SiMe3)
por: Jäschke T., et al.
Publicado: (2002-12-01)

THE MOLECULAR STRUCTURE OF [(C5H3NMeNH 2)2Li( μ-Br) 2Li[(C 5H3NMeNH 2)2], (C 5H3NMeNH 2 = 6-methyl-2-aminopyridine)
por: Jones, Cameron, et al.
Publicado: (2001-11-01)

The dehydropolymerization of H3B•NMeH2 to form polyaminoboranes using [Rh(Xantphos–alkyl)] catalysts
por: Adams, GM, et al.
Publicado: (2017)

A simple cobalt-based catalyst system for the controlled dehydropolymerisation of H3B·NMeH2 on the gram-scale
por: Boyd, T, et al.
Publicado: (2019)

The role of neutral Rh(PONOP)H, free NMe2H, boronium and ammonium salts in the dehydrocoupling of dimethylamine-borane using the cationic pincer [Rh(PONOP)(η2-H2)]+ catalyst†‡
por: Spearing-Ewyn, E, et al.
Publicado: (2019)

Mitochondrial NME6: A Paradigm Change within the NME/NDP Kinase Protein Family?
por: Bastien Proust, et al.
Publicado: (2024-07-01)

EtN=P(NMe2)N=P(NMe2)3: An efficient non-ionic base catalyst for the isomerization of allylic compounds and methylene-interrupted dienes
por: Wei Wu, et al.
Publicado: (2004-09-01)

ALUMINUM FILM GROWTH BY CHEMICAL VAPOR-DEPOSITION OF AIH3(NME3)2
por: Wee, A, et al.
Publicado: (1990)

NME proteins regulate class switch recombination
por: Zheng, Simin, et al.
Publicado: (2019)

The Montessori Method, and the Neurosequential Model in Education (NME)
por: Bernadette Phillips
Publicado: (2022-12-01)

Molecular structure of the functionalized bismuth alkoxide Bi[OC(CH2 NMe2)3]3
por: Kociok-Köhn Gabriele, et al.
Publicado: (2014-07-01)

NME6 is a phosphotransfer-inactive, monomeric NME/NDPK family member and functions in complexes at the interface of mitochondrial inner membrane and matrix
por: Bastien Proust, et al.
Publicado: (2021-11-01)

Revealing the P-B coupling event in the rhodium catalysed dehydrocoupling of phosphine-boranes H3B center dot PR2H (R = Bu-t, Ph)
por: Huertos, M, et al.
Publicado: (2013)

NME3 is a gatekeeper for DRP1-dependent mitophagy in hypoxia
por: Chih-Wei Chen, et al.
Publicado: (2024-03-01)

B-H activation at a rhodium(I) center: isolation of a bimetallic complex relevant to the transition-metal-catalyzed dehydrocoupling of amine-boranes.
por: Chaplin, AB, et al.
Publicado: (2010)

Further studies on the chemistry of tetramethylthiourea-platinum complexes: Evolution of cis-[PtCl{S=C(NMe2)(2)}(PPh3)(2)](+) to the dinuclear monothiocarbamato-sulfido complex [Pt-2(mu-S){mu-SC(O)NMe2}(PPh3)(4)](+)
por: Henderson, W., et al.
Publicado: (2015)

Crystal structure and Hirshfeld surface analysis of the new cyclodiphosphazane [EtNP(S)NMe2]2
por: Chokri Issaoui, et al.
Publicado: (2017-05-01)

CRYSTAL STRUCTURE OF [2,6- BIS(DIMETHYLAMINOMETHYL)PHENYL]DIPHENYLTIN HEXAFLUOROPHOSPHATE: {(C6H5)2Sn[C6H3[CH2NMe2)2-2,6}+ PF6
por: Ruzicka, Ales, et al.
Publicado: (2001-11-01)

NME2 reduces proliferation, migration and invasion of gastric cancer cells to limit metastasis.
por: Yan-fei Liu, et al.
Publicado: (2015-01-01)

SYNTHESIS AND STRUCTURE OF (NMe4)2[Hg(μ-Cl)(SC{O}Ph)2]2
por: Deivaraj, Theivanayagam C., et al.
Publicado: (2001-11-01)

Requirement of transcription factor NME2 for the maintenance of the stemness of gastric cancer stem-like cells
por: Yaxin Qi, et al.
Publicado: (2021-10-01)

THE STRUCTURE OF CO(ETA-C5H5)(2)(+) AND NME(4)(+) INTERCALATES OF MNPS3 - AN X-RAY, NEUTRON-DIFFRACTION, AND SOLID-STATE NMR-STUDY
por: Evans, J, et al.
Publicado: (1995)

Mono-Alkyl-Substituted Phosphinoboranes (HRP–BH<sub>2</sub>–NMe<sub>3</sub>) as Precursors for Poly(alkylphosphinoborane)s: Improved Synthesis and Comparative Study
por: Felix Lehnfeld, et al.
Publicado: (2023-09-01)

NmeCas9 is an intrinsically high-fidelity genome-editing platform
por: Nadia Amrani, et al.
Publicado: (2018-12-01)

NME5 frameshift variant in Alaskan Malamutes with primary ciliary dyskinesia.
por: Linda Anderegg, et al.
Publicado: (2019-09-01)

Mechanism-centric regulatory network identifies NME2 and MYC programs as markers of Enzalutamide resistance in CRPC
por: Sukanya Panja, et al.
Publicado: (2024-01-01)

Domain-inlaid Nme2Cas9 adenine base editors with improved activity and targeting scope
por: Nathan Bamidele, et al.
Publicado: (2024-02-01)

Efficient New Protocols for Converting Primary Amides into Nitriles Initiated by P(NMe2)3, PCl3, or P(OPh)3
por: Imen Talbi, et al.
Publicado: (2018-05-01)

Prognostic Value of NME1 (NM23-H1) in Patients with Digestive System Neoplasms: A Systematic Review and Meta-Analysis.
por: Wei Han, et al.
Publicado: (2016-01-01)

The clinical significance of accompanying NME on preoperative MR imaging in breast cancer patients.
por: Hye Mi Gweon, et al.
Publicado: (2017-01-01)

Dehydrocoupling of dimethylamine borane catalyzed by Rh(PCy3)2H2Cl.
por: Sewell, L, et al.
Publicado: (2013)

Crystal structure of trans-bis(P,P-dicyclohexyl-N-methyl-phosphinothioformamido) nickel(II),trans-{Ni[(c-C6H11)2PC(S)NMe]2}
por: Kramolowsky R., et al.
Publicado: (1997-12-01)

Crystal structure of trans-bis(P,P-dicyclohexyl-N-methyl-phosphinothioformamido) nickel(II),trans-{Ni[(c-C6H11)2PC(S)NMe]2}
por: Kramolowsky R., et al.
Publicado: (1997-12-01)

Research progress of Nme gene family and its application in oral squamous cell carcinoma
por: LIU Jia-peng, et al.
Publicado: (2016-07-01)

Regulation of metastasis suppressor NME1 by a key metabolic cofactor coenzyme A
por: Bess Yi Kun Yu, et al.
Publicado: (2021-08-01)