Desolvation of a novel microporous hydrogen-bonded framework: Characterization by in situ single-crystal and powder X-ray diffraction
Despite significant structural rearrangement upon desolvation of a three-dimensional molecular framework of hexaaquacobalt cations and redox- active functionalized tetrathiafulvalene anions (see the picture; the area filled with water molecules is shown in gray), monocrystallinity and microporosity...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
1998
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| _version_ | 1797094963851296768 |
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| author | Kepert, C Hesek, D Beer, P Rosseinsky, M |
| author_facet | Kepert, C Hesek, D Beer, P Rosseinsky, M |
| author_sort | Kepert, C |
| collection | OXFORD |
| description | Despite significant structural rearrangement upon desolvation of a three-dimensional molecular framework of hexaaquacobalt cations and redox- active functionalized tetrathiafulvalene anions (see the picture; the area filled with water molecules is shown in gray), monocrystallinity and microporosity are retained. X-ray analyses show that a unique combination of hydrogen bonds and π ·· π interactions within the framework gives this material a structural flexibility not seen in zeolites or their analogues. |
| first_indexed | 2024-03-07T04:21:13Z |
| format | Journal article |
| id | oxford-uuid:cb165068-cfe4-46b3-b144-2cb11c4e9daa |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T04:21:13Z |
| publishDate | 1998 |
| record_format | dspace |
| spelling | oxford-uuid:cb165068-cfe4-46b3-b144-2cb11c4e9daa2022-03-27T07:12:14ZDesolvation of a novel microporous hydrogen-bonded framework: Characterization by in situ single-crystal and powder X-ray diffractionJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:cb165068-cfe4-46b3-b144-2cb11c4e9daaEnglishSymplectic Elements at Oxford1998Kepert, CHesek, DBeer, PRosseinsky, MDespite significant structural rearrangement upon desolvation of a three-dimensional molecular framework of hexaaquacobalt cations and redox- active functionalized tetrathiafulvalene anions (see the picture; the area filled with water molecules is shown in gray), monocrystallinity and microporosity are retained. X-ray analyses show that a unique combination of hydrogen bonds and π ·· π interactions within the framework gives this material a structural flexibility not seen in zeolites or their analogues. |
| spellingShingle | Kepert, C Hesek, D Beer, P Rosseinsky, M Desolvation of a novel microporous hydrogen-bonded framework: Characterization by in situ single-crystal and powder X-ray diffraction |
| title | Desolvation of a novel microporous hydrogen-bonded framework: Characterization by in situ single-crystal and powder X-ray diffraction |
| title_full | Desolvation of a novel microporous hydrogen-bonded framework: Characterization by in situ single-crystal and powder X-ray diffraction |
| title_fullStr | Desolvation of a novel microporous hydrogen-bonded framework: Characterization by in situ single-crystal and powder X-ray diffraction |
| title_full_unstemmed | Desolvation of a novel microporous hydrogen-bonded framework: Characterization by in situ single-crystal and powder X-ray diffraction |
| title_short | Desolvation of a novel microporous hydrogen-bonded framework: Characterization by in situ single-crystal and powder X-ray diffraction |
| title_sort | desolvation of a novel microporous hydrogen bonded framework characterization by in situ single crystal and powder x ray diffraction |
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