Synthesis and characterization of a bimetallic boratabenzene cobalt complex

Reaction of 1,4-(BBr 2) 2C 6H 4 with cobaltocene gives a bimetallic cobalt complex with cyclopentadienyl and boratabenzene ligands. Oxidation allows the dicationic dicobalt(III) complex to be isolated; the bis(hexafluorophosphate) salt has been structurally characterized. Variable-temperature magnet...

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Автори: Hascall, T, Beck, V, Barlow, S, Cowley, A, O'Hare, D
Формат: Journal article
Мова:English
Опубліковано: 2004
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author Hascall, T
Beck, V
Barlow, S
Cowley, A
O'Hare, D
author_facet Hascall, T
Beck, V
Barlow, S
Cowley, A
O'Hare, D
author_sort Hascall, T
collection OXFORD
description Reaction of 1,4-(BBr 2) 2C 6H 4 with cobaltocene gives a bimetallic cobalt complex with cyclopentadienyl and boratabenzene ligands. Oxidation allows the dicationic dicobalt(III) complex to be isolated; the bis(hexafluorophosphate) salt has been structurally characterized. Variable-temperature magnetic susceptibility measurements on the neutral dicobalt(II) complex showed substantial deviation from the Curie -Weiss law; a fit to the Bleaney-Bowers equation for a singlet ground state and a triplet excited state gave an exchange interaction of J = ca. -28 cm -1. Electrochemical studies, as well as near-infrared data on the mixed-valence species, suggest that the interaction between the metal centers is weak.
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spelling oxford-uuid:cb3069a8-bcf1-469c-921c-6d1c37db87b12022-03-27T07:12:55ZSynthesis and characterization of a bimetallic boratabenzene cobalt complexJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:cb3069a8-bcf1-469c-921c-6d1c37db87b1EnglishSymplectic Elements at Oxford2004Hascall, TBeck, VBarlow, SCowley, AO'Hare, DReaction of 1,4-(BBr 2) 2C 6H 4 with cobaltocene gives a bimetallic cobalt complex with cyclopentadienyl and boratabenzene ligands. Oxidation allows the dicationic dicobalt(III) complex to be isolated; the bis(hexafluorophosphate) salt has been structurally characterized. Variable-temperature magnetic susceptibility measurements on the neutral dicobalt(II) complex showed substantial deviation from the Curie -Weiss law; a fit to the Bleaney-Bowers equation for a singlet ground state and a triplet excited state gave an exchange interaction of J = ca. -28 cm -1. Electrochemical studies, as well as near-infrared data on the mixed-valence species, suggest that the interaction between the metal centers is weak.
spellingShingle Hascall, T
Beck, V
Barlow, S
Cowley, A
O'Hare, D
Synthesis and characterization of a bimetallic boratabenzene cobalt complex
title Synthesis and characterization of a bimetallic boratabenzene cobalt complex
title_full Synthesis and characterization of a bimetallic boratabenzene cobalt complex
title_fullStr Synthesis and characterization of a bimetallic boratabenzene cobalt complex
title_full_unstemmed Synthesis and characterization of a bimetallic boratabenzene cobalt complex
title_short Synthesis and characterization of a bimetallic boratabenzene cobalt complex
title_sort synthesis and characterization of a bimetallic boratabenzene cobalt complex
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