Synthesis and characterization of a bimetallic boratabenzene cobalt complex

Reaction of 1,4-(BBr 2) 2C 6H 4 with cobaltocene gives a bimetallic cobalt complex with cyclopentadienyl and boratabenzene ligands. Oxidation allows the dicationic dicobalt(III) complex to be isolated; the bis(hexafluorophosphate) salt has been structurally characterized. Variable-temperature magnet...

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Hlavní autoři: Hascall, T, Beck, V, Barlow, S, Cowley, A, O'Hare, D
Médium: Journal article
Jazyk:English
Vydáno: 2004