Replacing dichloroethane as a solvent for rhodium-catalysed intermolecular alkyne hydroacylation reactions: the utility of propylene carbonate

Replacing dichloroethane as a solvent for rhodium-catalysed intermolecular alkyne hydroacylation reactions: the utility of propylene carbonate

Propylene carbonate is an excellent solvent for rhodium-catalysed intermolecular alkyne hydroacylation reactions, allowing a variety of β-S-aldehydes and alkynes to be combined in high yields, to deliver enone products. The effective use of propylene carbonate removes the need to employ dichloroetha...

Bibliografske podrobnosti
Main Authors:	Lenden, P, Ylioja, P, Gonzalez-Rodriguez, C, Entwistle, D, Willis, M
Format:	Journal article
Jezik:	English
Izdano:	2011

Podobne knjige/članki

Tandem catalytic processes involving Rhodium-catalysed intermolecular hydroacylation
od: Lenden, P
Izdano: (2011)

Rhodium catalysed hydroacylation reactions in the synthesis of heterocycles
od: Ylioja, P
Izdano: (2011)

Rhodium-catalysed linear-selective alkyne hydroacylation.
od: Poingdestre, S, et al.
Izdano: (2012)

Controlling selectivity in the rhodium-catalysed intermolecular hydroacylation reaction
od: Pawley, R
Izdano: (2012)

Mechanistic studies of rhodium-catalysed intermolecular hydroacylation
od: Barwick-Silk, J
Izdano: (2018)

Rhodium-catalysed intermolecular alkyne hydroacylation: the enantioselective synthesis of α- and β-substituted ketones by kinetic resolution.
od: González-Rodríguez, C, et al.
Izdano: (2010)

An alkyne hydroacylation route to highly substituted furans.
od: Lenden, P, et al.
Izdano: (2011)

Rhodium(I) catalysis for intermolecular alkyne hydroacylation and desymmetrisation
od: Moseley, D
Izdano: (2022)

Traceless chelation-controlled rhodium-catalyzed intermolecular alkene and alkyne hydroacylation.
od: Hooper, J, et al.
Izdano: (2013)

Rhodium-catalyzed enantioselective intermolecular hydroacylation reactions
od: Gonzalez-Rodriguez, C, et al.
Izdano: (2011)

Exploiting carbonyl groups to control intermolecular rhodium-catalyzed alkene and alkyne hydroacylation
od: Coxon, TJ, et al.
Izdano: (2017)

Rhodium (I) catalyzed intermolecular hydroacylation.
od: Sapmaz, S, et al.
Izdano: (2001)

α‐Amidoaldehydes as substrates in rhodium‐catalyzed intermolecular alkyne hydroacylation: The synthesis of α‐Amidoketones
od: Pal, R, et al.
Izdano: (2020)

a-Amidoaldehydes as substrates in rhodium-catalyzed intermolecular alkyne hydroacylation: The synthesis of a-amidoketones
od: Pal, R, et al.
Izdano: (2020)

Azine N-oxides as effective controlling groups for Rh-catalysed intermolecular alkyne hydroacylation
od: Moseley, DF, et al.
Izdano: (2021)

O-substituted alkyl aldehydes for rhodium-catalyzed intermolecular alkyne hydroacylation: the utility of methylthiomethyl ethers.
od: Parsons, SR, et al.
Izdano: (2011)

Exploring small bite-angle PNP and PCP ligands for the rhodium-catalysed intermolecular hydroacylation of b-s-substituted aldehydes with alkenes and alkynes
od: Pernik, I
Izdano: (2014)

Exploring and exploiting selectivity in Rhodium-catalysed hydroacylation reactions
od: Poingdestre, SJ
Izdano: (2012)

New applications of rhodium-catalysed hydroacylation
od: Iwumene, NUN
Izdano: (2022)

An enamine controlling group for rhodium-catalyzed intermolecular hydroacylation
od: Straker, R, et al.
Izdano: (2018)

Rhodium-catalyzed intermolecular chelation controlled alkene and alkyne hydroacylation: synthetic scope of beta-S-substituted aldehyde substrates.
od: Willis, M, et al.
Izdano: (2006)

Studies toward the application and development of rhodium-catalysed hydroacylation reactions
od: Neuhaus, J
Izdano: (2016)

Diversely substituted quinolines via rhodium-catalyzed alkyne hydroacylation
od: Willis, M, et al.
Izdano: (2016)

Rhodium-catalysed hydroacylation or reductive aldol reactions: a ligand dependent switch of reactivity.
od: Osborne, J, et al.
Izdano: (2008)

Applications of rhodium-catalysed hydroacylation in heterocycle synthesis
od: Majhail, M
Izdano: (2016)

New reactivity and selectivity in rhodium-catalysed hydroacylation
od: Pal, R
Izdano: (2020)

Exploiting rhodium-catalysed ynamide hydroacylation as a platform for divergent heterocycle synthesis
od: Straker, R, et al.
Izdano: (2017)

Chelation-controlled intermolecular alkene and alkyne hydroacylation: the utility of beta-thioacetal aldehydes.
od: Willis, M, et al.
Izdano: (2005)

Investigating rhodium-catalysed hydroacylation and carbon-carbon bond activation
od: Coxon, T
Izdano: (2017)

2-Aminobenzaldehydes as versatile substrates for rhodium-catalyzed alkyne hydroacylation: application to dihydroquinolone synthesis.
od: Castaing, M, et al.
Izdano: (2013)

Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch.
od: González-Rodríguez, C, et al.
Izdano: (2011)

Hydroacylation of Alkenes, Alkynes, and Allenes
od: Willis, M
Izdano: (2014)

Intermolecular rhodium catalyzed hydroacylation of allenes: the regioselective synthesis of beta,gamma-unsaturated ketones
od: Randell-Sly, H, et al.
Izdano: (2009)

Intermolecular hydroacylation: high activity rhodium catalysts containing small-bite-angle diphosphine ligands.
od: Chaplin, AB, et al.
Izdano: (2012)

Intermolecular Alkyne Hydroacylation. Mechanistic Insight from the Isolation of the Vinyl Intermediate That Precedes Reductive Elimination
od: Pawley, R, et al.
Izdano: (2012)

Catalytic enantioselective intermolecular hydroacylation: rhodium-catalyzed combination of beta-S-aldehydes and 1,3-disubstituted allenes.
od: Osborne, J, et al.
Izdano: (2008)

Transition metal catalyzed alkene and alkyne hydroacylation.
od: Willis, M
Izdano: (2010)

Synthesis of α,β-unsaturated ketones through nickel-catalysed aldehyde-free hydroacylation of alkynes
od: Joon Ho Rhlee, et al.
Izdano: (2022-02-01)

Exploring Small Bite-Angle Ligands for the Rhodium-Catalyzed Intermolecular Hydroacylation of beta-S-Substituted Aldehydes with 1-Octene and 1-Octyne
od: Pernik, I, et al.
Izdano: (2012)

Sequential catalysis: Exploiting a single rhodium(I) catalyst to promote an alkyne hydroacylation–aryl boronic acid conjugate addition sequence
od: Fernández, M, et al.
Izdano: (2016)