The synthesis of (+)-pericosine B

The first synthesis of (+)-pericosine B is described; this takes seven steps and proceeds in 10% overall yield. The key step in our work is a hydrogen-bonding controlled contra-steric dihydroxylation reaction using osmium tetroxide and an amine promoter. The absolute stereochemistry of the natural p...

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Hlavní autoři: Donohoe, T, Blades, K, Helliwell, M, Waring, M, Newcombe, N
Médium: Journal article
Jazyk:English
Vydáno: 1998