Axial dispersion via shear-enhanced diffusion in colloidal suspensions

The familiar example of Taylor dispersion of molecular solutes is extended to describe colloidal suspensions, where the fluctuations that contribute to dispersion arise from hydrodynamic interactions. The generic scheme is illustrated for a suspension of particles in a pressure-driven pipe flow, wit...

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Main Authors: Griffiths, I, Stone, H
Format: Journal article
Language:English
Published: 2012
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author Griffiths, I
Stone, H
author_facet Griffiths, I
Stone, H
author_sort Griffiths, I
collection OXFORD
description The familiar example of Taylor dispersion of molecular solutes is extended to describe colloidal suspensions, where the fluctuations that contribute to dispersion arise from hydrodynamic interactions. The generic scheme is illustrated for a suspension of particles in a pressure-driven pipe flow, with a concentration-dependent diffusivity that captures both the shear-induced and Brownian contributions. The effect of the cross-stream migration via shear-induced diffusion is shown to dramatically reduce the axial dispersion predicted by classical Taylor dispersion for a molecular solute. Analytic and numerical solutions are presented that illustrate the effect of the concentration dependence of this nonlinear hydrodynamic mechanism. Copyright © EPLA, 2012.
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spelling oxford-uuid:cc13d45d-7be2-44e0-94fe-8d43d7ccc5782022-03-27T07:19:15ZAxial dispersion via shear-enhanced diffusion in colloidal suspensionsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:cc13d45d-7be2-44e0-94fe-8d43d7ccc578EnglishSymplectic Elements at Oxford2012Griffiths, IStone, HThe familiar example of Taylor dispersion of molecular solutes is extended to describe colloidal suspensions, where the fluctuations that contribute to dispersion arise from hydrodynamic interactions. The generic scheme is illustrated for a suspension of particles in a pressure-driven pipe flow, with a concentration-dependent diffusivity that captures both the shear-induced and Brownian contributions. The effect of the cross-stream migration via shear-induced diffusion is shown to dramatically reduce the axial dispersion predicted by classical Taylor dispersion for a molecular solute. Analytic and numerical solutions are presented that illustrate the effect of the concentration dependence of this nonlinear hydrodynamic mechanism. Copyright © EPLA, 2012.
spellingShingle Griffiths, I
Stone, H
Axial dispersion via shear-enhanced diffusion in colloidal suspensions
title Axial dispersion via shear-enhanced diffusion in colloidal suspensions
title_full Axial dispersion via shear-enhanced diffusion in colloidal suspensions
title_fullStr Axial dispersion via shear-enhanced diffusion in colloidal suspensions
title_full_unstemmed Axial dispersion via shear-enhanced diffusion in colloidal suspensions
title_short Axial dispersion via shear-enhanced diffusion in colloidal suspensions
title_sort axial dispersion via shear enhanced diffusion in colloidal suspensions
work_keys_str_mv AT griffithsi axialdispersionviashearenhanceddiffusionincolloidalsuspensions
AT stoneh axialdispersionviashearenhanceddiffusionincolloidalsuspensions