Access to enhanced differences in Marcus–Hush and Butler–Volmer electron transfer theories by systematic analysis of higher order AC harmonics
The potential-dependences of the rate constants associated with heterogeneous electron transfer predicted by the empirically based Butler-Volmer and fundamentally based Marcus-Hush formalisms are well documented for dc cyclic voltammetry. However, differences are often subtle, so, presumably on the...
المؤلفون الرئيسيون: | Gillow, K, Stevenson, G, Baker, R, Kennedy, G, Bond, A, Gavaghan, D |
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مؤلفون آخرون: | Spencelayh, M |
التنسيق: | Journal article |
اللغة: | English |
منشور في: |
Royal Society of Chemistry
2012
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مواد مشابهة
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Experimental comparison of the Butler-Volmer and Marcus-Hush-Chidsey formalisms of electrode kinetics: The reduction of cyclooctatetraene at mercury hemispherical electrodes via cyclic and square wave voltammetries
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Experimental comparison of the Butler-Volmer and Marcus-Hush-Chidsey formalisms of electrode kinetics: The reduction of cyclooctatetraene at mercury hemispherical electrodes via cyclic and square wave voltammetries
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One electron oxygen reduction in room temperature ionic liquids: A comparative study of Butler-Volmer and Symmetric Marcus-Hush theories using microdisc electrodes
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