Access to enhanced differences in Marcus–Hush and Butler–Volmer electron transfer theories by systematic analysis of higher order AC harmonics
The potential-dependences of the rate constants associated with heterogeneous electron transfer predicted by the empirically based Butler-Volmer and fundamentally based Marcus-Hush formalisms are well documented for dc cyclic voltammetry. However, differences are often subtle, so, presumably on the...
| Main Authors: | , , , , , |
|---|---|
| 其他作者: | |
| 格式: | Journal article |
| 语言: | English |
| 出版: |
Royal Society of Chemistry
2012
|