ROTATIONAL SPECTRA OF RARE-GAS NITRIC-OXIDE VANDERWAALS MOLECULES .1. THEORY OF THE ROTATIONAL ENERGY-LEVELS

ROTATIONAL SPECTRA OF RARE-GAS NITRIC-OXIDE VANDERWAALS MOLECULES .1. THEORY OF THE ROTATIONAL ENERGY-LEVELS

A new Hamiltonian is presented for the analysis of the spectra of open-shell van der Waals molecules with a nonlinear geometry. The theory is similar to that already developed for linear molecules with orbital angular momentum but generalized to asymmetric tops where there is only a slight quenching...

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Những tác giả chính: Mills, P, Western, C, Howard, B
Định dạng: Journal article
Ngôn ngữ:English
Được phát hành: 1986
Miêu tả
Tóm tắt:A new Hamiltonian is presented for the analysis of the spectra of open-shell van der Waals molecules with a nonlinear geometry. The theory is similar to that already developed for linear molecules with orbital angular momentum but generalized to asymmetric tops where there is only a slight quenching of the orbital angular momentum. The resulting energy levels show a number of novel features including a rapid variation with angular geometry. Both fine structure and hyperfine effects are considered. © 1986 American Chemical Society.

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