Corrosion and hydrogen pickup mechanisms of zirconium alloys
<p>Zirconium alloy cladding isolates the nuclear fuel rods from water coolant in a nuclear fission reactor, but in this harsh environment experience high temperature aqueous corrosion and hydrogen pickup (HPU). The segregation of minor elements such as iron, niobium and antimony greatly affect...
| প্রধান লেখক: | |
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| অন্যান্য লেখক: | |
| বিন্যাস: | গবেষণাপত্র |
| ভাষা: | English |
| প্রকাশিত: |
2016
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| বিষয়গুলি: |
| _version_ | 1826297189395070976 |
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| author | Setiadinata, SB |
| author2 | Grovenor, C |
| author_facet | Grovenor, C Setiadinata, SB |
| author_sort | Setiadinata, SB |
| collection | OXFORD |
| description | <p>Zirconium alloy cladding isolates the nuclear fuel rods from water coolant in a nuclear fission reactor, but in this harsh environment experience high temperature aqueous corrosion and hydrogen pickup (HPU). The segregation of minor elements such as iron, niobium and antimony greatly affects the corrosion and HPU of Zr alloys, but often this segregation occurs at a scale too small for most characterisation techniques to observe. Atom probe tomography (APT) enables the 3D analysis of elemental distributions on the atomic scale using time-of-flight spectroscopy. .</p>
<p>The corrosion and HPU of Zr-Nb alloys with 0.5-2.5 wt% Nb were examined using APT. The oxygen-saturated metal region at the oxide/metal (O/M) interface increases with instantaneous oxidation rate and deuterium segregation to oxide grain boundaries and pores that probably contain hydrogen have been observed. The ratio of hydrogen isotopes showed that where the D-containing signal was higher, deuterium segregation to grain boundaries was more likely..</p>
<p>Fe around β-Nb particles and on metal grain boundaries is redistributed during oxidation. This redistribution results in Fe enrichment in the oxide which would correlate with the space charge compensation predicted to decrease HPU. During oxidation, Nb leaches out from the β-Nb precipitates to the oxide matrix. Preliminary analysis on Sb-containing samples has been carried out and weak Sb segregation to metal grain boundaries has been observed. Irradiation also causes redistribution of Fe and Nb, particularly Fe in the vicinity of oxide grain boundaries and Nb leaving the β-Nb particles under irradiation, resulting in the formation of small Nb clusters. The results of this study show that APT can observe changes of elemental distributions on the atomic scale which is vital to understanding how Zr alloys behaves during corrosion.</p> |
| first_indexed | 2024-03-07T04:27:47Z |
| format | Thesis |
| id | oxford-uuid:cd410674-7cb2-4ba4-a12c-9c99a9b20e33 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T04:27:47Z |
| publishDate | 2016 |
| record_format | dspace |
| spelling | oxford-uuid:cd410674-7cb2-4ba4-a12c-9c99a9b20e332022-03-27T07:27:20ZCorrosion and hydrogen pickup mechanisms of zirconium alloysThesishttp://purl.org/coar/resource_type/c_db06uuid:cd410674-7cb2-4ba4-a12c-9c99a9b20e33Atom-probe field ion microscopyMicroscopyCorrosionEnglishHyrax Deposit2016Setiadinata, SBGrovenor, CMoody, CBagot, P<p>Zirconium alloy cladding isolates the nuclear fuel rods from water coolant in a nuclear fission reactor, but in this harsh environment experience high temperature aqueous corrosion and hydrogen pickup (HPU). The segregation of minor elements such as iron, niobium and antimony greatly affects the corrosion and HPU of Zr alloys, but often this segregation occurs at a scale too small for most characterisation techniques to observe. Atom probe tomography (APT) enables the 3D analysis of elemental distributions on the atomic scale using time-of-flight spectroscopy. .</p> <p>The corrosion and HPU of Zr-Nb alloys with 0.5-2.5 wt% Nb were examined using APT. The oxygen-saturated metal region at the oxide/metal (O/M) interface increases with instantaneous oxidation rate and deuterium segregation to oxide grain boundaries and pores that probably contain hydrogen have been observed. The ratio of hydrogen isotopes showed that where the D-containing signal was higher, deuterium segregation to grain boundaries was more likely..</p> <p>Fe around β-Nb particles and on metal grain boundaries is redistributed during oxidation. This redistribution results in Fe enrichment in the oxide which would correlate with the space charge compensation predicted to decrease HPU. During oxidation, Nb leaches out from the β-Nb precipitates to the oxide matrix. Preliminary analysis on Sb-containing samples has been carried out and weak Sb segregation to metal grain boundaries has been observed. Irradiation also causes redistribution of Fe and Nb, particularly Fe in the vicinity of oxide grain boundaries and Nb leaving the β-Nb particles under irradiation, resulting in the formation of small Nb clusters. The results of this study show that APT can observe changes of elemental distributions on the atomic scale which is vital to understanding how Zr alloys behaves during corrosion.</p> |
| spellingShingle | Atom-probe field ion microscopy Microscopy Corrosion Setiadinata, SB Corrosion and hydrogen pickup mechanisms of zirconium alloys |
| title | Corrosion and hydrogen pickup mechanisms of zirconium alloys |
| title_full | Corrosion and hydrogen pickup mechanisms of zirconium alloys |
| title_fullStr | Corrosion and hydrogen pickup mechanisms of zirconium alloys |
| title_full_unstemmed | Corrosion and hydrogen pickup mechanisms of zirconium alloys |
| title_short | Corrosion and hydrogen pickup mechanisms of zirconium alloys |
| title_sort | corrosion and hydrogen pickup mechanisms of zirconium alloys |
| topic | Atom-probe field ion microscopy Microscopy Corrosion |
| work_keys_str_mv | AT setiadinatasb corrosionandhydrogenpickupmechanismsofzirconiumalloys |