Concise synthesis of calystegines B2 and B3via intramolecular Nozaki–Hiyama–Kishi reaction
The key step in the concise syntheses of calystegine B2 and its C-2 epimer calystegine B3 was the construction of cycloheptanone 8via an intramolecular Nozaki-Hiyama-Kishi (NHK) reaction of 9, an aldehyde containing a Z-vinyl iodide. Vinyl iodide 9 was obtained by the Stork olefination of aldehyde 1...
Full description
Bibliographic Details
| Main Authors: |
Wang, H,
Kato, A,
Kinami, K,
Li, Y,
Fleet, G,
Yu, C |
|---|
| Format: | Journal article
|
|---|
| Published: |
Royal Society of Chemistry
2016
|
|---|