Water adsorbancy of high surface area layered double hydroxides (AMO-LDHs)
Understanding the water adsorbancy of highly dispersed, high surface area layered double hydroxide (LDH) is of great importance as it directly relates to their hydrophobicity and subsequent use as additives in LDH-polymer nanocomposites. In this study, we have investigated the water vapour uptake re...
| Main Authors: | , , , |
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| Format: | Journal article |
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Royal Society of Chemistry
2018
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| _version_ | 1797095455643926528 |
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| author | Chen, C Ruengkajorn, K Buffet, J O'Hare, D |
| author_facet | Chen, C Ruengkajorn, K Buffet, J O'Hare, D |
| author_sort | Chen, C |
| collection | OXFORD |
| description | Understanding the water adsorbancy of highly dispersed, high surface area layered double hydroxide (LDH) is of great importance as it directly relates to their hydrophobicity and subsequent use as additives in LDH-polymer nanocomposites. In this study, we have investigated the water vapour uptake response of highly dispersed, high surface area aqueous miscible organic-LDHs (AMO-LDHs) in two relative humidity atmospheres (RH99 and RH60) at 20 °C. We observed that AMO-Mg3Al-CO3and AMO-Zn2MgAl-CO3exhibited very high water vapour uptake in an RH99 atmosphere at 20 °C (56 wt% and 20 wt% for Mg3Al-CO3and Zn2MgAl-CO3LDH respectively after 120 h). The crystallinity in both ab-plane and c-axis of the LDHs increased with increasing exposure uptake. The water vapour adsorption capacity of the AMO-LDHs can be dramatically reduced by treatment with stearic acid. |
| first_indexed | 2024-03-07T04:28:03Z |
| format | Journal article |
| id | oxford-uuid:cd55d3df-e045-4b02-981b-616c42312109 |
| institution | University of Oxford |
| last_indexed | 2024-03-07T04:28:03Z |
| publishDate | 2018 |
| publisher | Royal Society of Chemistry |
| record_format | dspace |
| spelling | oxford-uuid:cd55d3df-e045-4b02-981b-616c423121092022-03-27T07:28:00ZWater adsorbancy of high surface area layered double hydroxides (AMO-LDHs)Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:cd55d3df-e045-4b02-981b-616c42312109Symplectic Elements at OxfordRoyal Society of Chemistry2018Chen, CRuengkajorn, KBuffet, JO'Hare, DUnderstanding the water adsorbancy of highly dispersed, high surface area layered double hydroxide (LDH) is of great importance as it directly relates to their hydrophobicity and subsequent use as additives in LDH-polymer nanocomposites. In this study, we have investigated the water vapour uptake response of highly dispersed, high surface area aqueous miscible organic-LDHs (AMO-LDHs) in two relative humidity atmospheres (RH99 and RH60) at 20 °C. We observed that AMO-Mg3Al-CO3and AMO-Zn2MgAl-CO3exhibited very high water vapour uptake in an RH99 atmosphere at 20 °C (56 wt% and 20 wt% for Mg3Al-CO3and Zn2MgAl-CO3LDH respectively after 120 h). The crystallinity in both ab-plane and c-axis of the LDHs increased with increasing exposure uptake. The water vapour adsorption capacity of the AMO-LDHs can be dramatically reduced by treatment with stearic acid. |
| spellingShingle | Chen, C Ruengkajorn, K Buffet, J O'Hare, D Water adsorbancy of high surface area layered double hydroxides (AMO-LDHs) |
| title | Water adsorbancy of high surface area layered double hydroxides (AMO-LDHs) |
| title_full | Water adsorbancy of high surface area layered double hydroxides (AMO-LDHs) |
| title_fullStr | Water adsorbancy of high surface area layered double hydroxides (AMO-LDHs) |
| title_full_unstemmed | Water adsorbancy of high surface area layered double hydroxides (AMO-LDHs) |
| title_short | Water adsorbancy of high surface area layered double hydroxides (AMO-LDHs) |
| title_sort | water adsorbancy of high surface area layered double hydroxides amo ldhs |
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