Dearomatisation of o-xylene by P450BM3 (CYP102A1).
The oxidation of o-xylene by P450(BM3) from Bacillus megaterium yields, in addition to the products formed by microsomal P450s, two metabolites containing an NIH-shifted methyl group, one of which lacks the aromatic character of the substrate. The failure of the epoxide precursor of these two produc...
Main Authors: | , , , |
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Format: | Journal article |
Language: | English |
Published: |
2011
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