Reactions of Cp(NAr)NbMe2 with H-2 and HSiMe2Cl. Molecular structure of [CpNb(mu-NAr)Me](2) (Ar=2,6-(C6H3Pr2)-Pr-i)
Reactions of Cp(NAr)NbMe2 with H2 and HSiMe2Cl are described. With H2 (1 atm) an apparent σ-bond metathesis process is accompanied by reduction to form the binuclear, metal-metal bonded species [CpNb(μ-NAr)Me]2 (Nb-Nb=2.6852(4) Å). With HSiMe2Cl (excess) Cp(NAr)NbMeCl is obtained in quantitative yie...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2001
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| _version_ | 1826297573114118144 |
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| author | Nikonov, G Mountford, P Kuzmina, L Howard, J Lemenovskii, D Roitershtein, D |
| author_facet | Nikonov, G Mountford, P Kuzmina, L Howard, J Lemenovskii, D Roitershtein, D |
| author_sort | Nikonov, G |
| collection | OXFORD |
| description | Reactions of Cp(NAr)NbMe2 with H2 and HSiMe2Cl are described. With H2 (1 atm) an apparent σ-bond metathesis process is accompanied by reduction to form the binuclear, metal-metal bonded species [CpNb(μ-NAr)Me]2 (Nb-Nb=2.6852(4) Å). With HSiMe2Cl (excess) Cp(NAr)NbMeCl is obtained in quantitative yield. © 2001 Elsevier Science B.V. |
| first_indexed | 2024-03-07T04:33:42Z |
| format | Journal article |
| id | oxford-uuid:cf337c44-903b-493c-a1a1-dd9ff1c56aed |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T04:33:42Z |
| publishDate | 2001 |
| record_format | dspace |
| spelling | oxford-uuid:cf337c44-903b-493c-a1a1-dd9ff1c56aed2022-03-27T07:40:51ZReactions of Cp(NAr)NbMe2 with H-2 and HSiMe2Cl. Molecular structure of [CpNb(mu-NAr)Me](2) (Ar=2,6-(C6H3Pr2)-Pr-i)Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:cf337c44-903b-493c-a1a1-dd9ff1c56aedEnglishSymplectic Elements at Oxford2001Nikonov, GMountford, PKuzmina, LHoward, JLemenovskii, DRoitershtein, DReactions of Cp(NAr)NbMe2 with H2 and HSiMe2Cl are described. With H2 (1 atm) an apparent σ-bond metathesis process is accompanied by reduction to form the binuclear, metal-metal bonded species [CpNb(μ-NAr)Me]2 (Nb-Nb=2.6852(4) Å). With HSiMe2Cl (excess) Cp(NAr)NbMeCl is obtained in quantitative yield. © 2001 Elsevier Science B.V. |
| spellingShingle | Nikonov, G Mountford, P Kuzmina, L Howard, J Lemenovskii, D Roitershtein, D Reactions of Cp(NAr)NbMe2 with H-2 and HSiMe2Cl. Molecular structure of [CpNb(mu-NAr)Me](2) (Ar=2,6-(C6H3Pr2)-Pr-i) |
| title | Reactions of Cp(NAr)NbMe2 with H-2 and HSiMe2Cl. Molecular structure of [CpNb(mu-NAr)Me](2) (Ar=2,6-(C6H3Pr2)-Pr-i) |
| title_full | Reactions of Cp(NAr)NbMe2 with H-2 and HSiMe2Cl. Molecular structure of [CpNb(mu-NAr)Me](2) (Ar=2,6-(C6H3Pr2)-Pr-i) |
| title_fullStr | Reactions of Cp(NAr)NbMe2 with H-2 and HSiMe2Cl. Molecular structure of [CpNb(mu-NAr)Me](2) (Ar=2,6-(C6H3Pr2)-Pr-i) |
| title_full_unstemmed | Reactions of Cp(NAr)NbMe2 with H-2 and HSiMe2Cl. Molecular structure of [CpNb(mu-NAr)Me](2) (Ar=2,6-(C6H3Pr2)-Pr-i) |
| title_short | Reactions of Cp(NAr)NbMe2 with H-2 and HSiMe2Cl. Molecular structure of [CpNb(mu-NAr)Me](2) (Ar=2,6-(C6H3Pr2)-Pr-i) |
| title_sort | reactions of cp nar nbme2 with h 2 and hsime2cl molecular structure of cpnb mu nar me 2 ar 2 6 c6h3pr2 pr i |
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