Probing the surface of aqueous surfactant-perfume mixed solutions during perfume evaporation

The rate of release or evaporation of perfume molecules from surfaces is a key factor in determining the impact of the perfume in a range of applications relating to home and personal care products. For mixtures of the anionic surfactant sodium dodecylsulfate and the model perfume linalool the rate...

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Main Authors: Penfold, J, Thomas, R, Bradbury, R, Tucker, I, Petkov, J, Jones, C, Webster, J
Format: Journal article
Published: Elsevier 2017
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author Penfold, J
Thomas, R
Bradbury, R
Tucker, I
Petkov, J
Jones, C
Webster, J
author_facet Penfold, J
Thomas, R
Bradbury, R
Tucker, I
Petkov, J
Jones, C
Webster, J
author_sort Penfold, J
collection OXFORD
description The rate of release or evaporation of perfume molecules from surfaces is a key factor in determining the impact of the perfume in a range of applications relating to home and personal care products. For mixtures of the anionic surfactant sodium dodecylsulfate and the model perfume linalool the rate of change of adsorption with time due to forced air flow over a fixed headspace was evaluated using neutron reflectivity over a period of up to ∼250 min. The measurements were made in the limit of the high flow rates where the evaporation is independent of the air flow rate. The amount of perfume at the interface decreases with time, and this occurs at a faster rate as the initial amount of perfume in solution is decreased. The variation of the perfume adsorption with time for different surfactant/perfume solution compositions illustrates the increasing importance of diffusion to the surface as the perfume concentration in solution decreases.
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spelling oxford-uuid:cf927a3b-8306-41f4-9d1d-64984e7b12972022-03-27T07:43:48ZProbing the surface of aqueous surfactant-perfume mixed solutions during perfume evaporationJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:cf927a3b-8306-41f4-9d1d-64984e7b1297Symplectic Elements at OxfordElsevier2017Penfold, JThomas, RBradbury, RTucker, IPetkov, JJones, CWebster, JThe rate of release or evaporation of perfume molecules from surfaces is a key factor in determining the impact of the perfume in a range of applications relating to home and personal care products. For mixtures of the anionic surfactant sodium dodecylsulfate and the model perfume linalool the rate of change of adsorption with time due to forced air flow over a fixed headspace was evaluated using neutron reflectivity over a period of up to ∼250 min. The measurements were made in the limit of the high flow rates where the evaporation is independent of the air flow rate. The amount of perfume at the interface decreases with time, and this occurs at a faster rate as the initial amount of perfume in solution is decreased. The variation of the perfume adsorption with time for different surfactant/perfume solution compositions illustrates the increasing importance of diffusion to the surface as the perfume concentration in solution decreases.
spellingShingle Penfold, J
Thomas, R
Bradbury, R
Tucker, I
Petkov, J
Jones, C
Webster, J
Probing the surface of aqueous surfactant-perfume mixed solutions during perfume evaporation
title Probing the surface of aqueous surfactant-perfume mixed solutions during perfume evaporation
title_full Probing the surface of aqueous surfactant-perfume mixed solutions during perfume evaporation
title_fullStr Probing the surface of aqueous surfactant-perfume mixed solutions during perfume evaporation
title_full_unstemmed Probing the surface of aqueous surfactant-perfume mixed solutions during perfume evaporation
title_short Probing the surface of aqueous surfactant-perfume mixed solutions during perfume evaporation
title_sort probing the surface of aqueous surfactant perfume mixed solutions during perfume evaporation
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AT thomasr probingthesurfaceofaqueoussurfactantperfumemixedsolutionsduringperfumeevaporation
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AT tuckeri probingthesurfaceofaqueoussurfactantperfumemixedsolutionsduringperfumeevaporation
AT petkovj probingthesurfaceofaqueoussurfactantperfumemixedsolutionsduringperfumeevaporation
AT jonesc probingthesurfaceofaqueoussurfactantperfumemixedsolutionsduringperfumeevaporation
AT websterj probingthesurfaceofaqueoussurfactantperfumemixedsolutionsduringperfumeevaporation