Total charge amount as indicator for the degradation of small molecule organic solar cells

We show that the number of extracted charge carriers is a suitable measure to compare lifetime measurements on organic solar cells at different intensities. In detail, we used pin-structures with active layers containing a bulk heterojunction of Zincphthalocyanine (ZnPc) and C<sub>60</sub&g...

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Main Authors: Hermenau, M, Scholz, S, Leo, K, Riede, M
Format: Journal article
Language:English
Published: Elsevier 2011
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author Hermenau, M
Scholz, S
Leo, K
Riede, M
author_facet Hermenau, M
Scholz, S
Leo, K
Riede, M
author_sort Hermenau, M
collection OXFORD
description We show that the number of extracted charge carriers is a suitable measure to compare lifetime measurements on organic solar cells at different intensities. In detail, we used pin-structures with active layers containing a bulk heterojunction of Zincphthalocyanine (ZnPc) and C<sub>60</sub>. Extended lifetime measurements under constant monochromatic or white illumination at defined temperatures of 50 °C or 90 °C are done. On the one hand, we show that the number of extracted charge carriers is important to determine the degree of degradation. On the other hand, our results show that the energy of irradiated photons is significant for accelerated measurements. This is an major advantage for the realisation of accelerated lifetime measurements. Additionally, we find that not single charge carriers, but excitons cause the degradation of the observed solar cells. © 2010 Elsevier B.V. All rights reserved.
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spelling oxford-uuid:cfe1afbc-ad6b-4561-bb12-e09ea69253552022-03-27T07:46:02ZTotal charge amount as indicator for the degradation of small molecule organic solar cellsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:cfe1afbc-ad6b-4561-bb12-e09ea6925355EnglishSymplectic Elements at OxfordElsevier2011Hermenau, MScholz, SLeo, KRiede, MWe show that the number of extracted charge carriers is a suitable measure to compare lifetime measurements on organic solar cells at different intensities. In detail, we used pin-structures with active layers containing a bulk heterojunction of Zincphthalocyanine (ZnPc) and C<sub>60</sub>. Extended lifetime measurements under constant monochromatic or white illumination at defined temperatures of 50 °C or 90 °C are done. On the one hand, we show that the number of extracted charge carriers is important to determine the degree of degradation. On the other hand, our results show that the energy of irradiated photons is significant for accelerated measurements. This is an major advantage for the realisation of accelerated lifetime measurements. Additionally, we find that not single charge carriers, but excitons cause the degradation of the observed solar cells. © 2010 Elsevier B.V. All rights reserved.
spellingShingle Hermenau, M
Scholz, S
Leo, K
Riede, M
Total charge amount as indicator for the degradation of small molecule organic solar cells
title Total charge amount as indicator for the degradation of small molecule organic solar cells
title_full Total charge amount as indicator for the degradation of small molecule organic solar cells
title_fullStr Total charge amount as indicator for the degradation of small molecule organic solar cells
title_full_unstemmed Total charge amount as indicator for the degradation of small molecule organic solar cells
title_short Total charge amount as indicator for the degradation of small molecule organic solar cells
title_sort total charge amount as indicator for the degradation of small molecule organic solar cells
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