Polyselenides on the route to electrodeposited selenium
The electrochemical oxidation of aqueous solutions of hydrogen selenide (HSe − ) and of hydrogen polyselenide ions (HSe x− ) on glassy carbon electrodes at pH = 9.2 is reported. In both cases, the oxidation leads to deposits of selenium. The role of polyselenides as intermediates in the process is d...
| Main Authors: | , , , |
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| Format: | Journal article |
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Elsevier
2019
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| _version_ | 1797096032408961024 |
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| author | Rasche, B Amin, H Clarke, S Compton, R |
| author_facet | Rasche, B Amin, H Clarke, S Compton, R |
| author_sort | Rasche, B |
| collection | OXFORD |
| description | The electrochemical oxidation of aqueous solutions of hydrogen selenide (HSe − ) and of hydrogen polyselenide ions (HSe x− ) on glassy carbon electrodes at pH = 9.2 is reported. In both cases, the oxidation leads to deposits of selenium. The role of polyselenides as intermediates in the process is demonstrated. At 25 °C amorphous selenium is formed whereas at 70 °C crystalline selenium is deposited. The possible use of selenium films for technological purposes is discussed. |
| first_indexed | 2024-03-07T04:36:17Z |
| format | Journal article |
| id | oxford-uuid:d00a6f23-e9a7-4a1b-a2f4-8b944aaa007e |
| institution | University of Oxford |
| last_indexed | 2024-03-07T04:36:17Z |
| publishDate | 2019 |
| publisher | Elsevier |
| record_format | dspace |
| spelling | oxford-uuid:d00a6f23-e9a7-4a1b-a2f4-8b944aaa007e2022-03-27T07:47:04ZPolyselenides on the route to electrodeposited seleniumJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:d00a6f23-e9a7-4a1b-a2f4-8b944aaa007eSymplectic Elements at OxfordElsevier2019Rasche, BAmin, HClarke, SCompton, RThe electrochemical oxidation of aqueous solutions of hydrogen selenide (HSe − ) and of hydrogen polyselenide ions (HSe x− ) on glassy carbon electrodes at pH = 9.2 is reported. In both cases, the oxidation leads to deposits of selenium. The role of polyselenides as intermediates in the process is demonstrated. At 25 °C amorphous selenium is formed whereas at 70 °C crystalline selenium is deposited. The possible use of selenium films for technological purposes is discussed. |
| spellingShingle | Rasche, B Amin, H Clarke, S Compton, R Polyselenides on the route to electrodeposited selenium |
| title | Polyselenides on the route to electrodeposited selenium |
| title_full | Polyselenides on the route to electrodeposited selenium |
| title_fullStr | Polyselenides on the route to electrodeposited selenium |
| title_full_unstemmed | Polyselenides on the route to electrodeposited selenium |
| title_short | Polyselenides on the route to electrodeposited selenium |
| title_sort | polyselenides on the route to electrodeposited selenium |
| work_keys_str_mv | AT rascheb polyselenidesontheroutetoelectrodepositedselenium AT aminh polyselenidesontheroutetoelectrodepositedselenium AT clarkes polyselenidesontheroutetoelectrodepositedselenium AT comptonr polyselenidesontheroutetoelectrodepositedselenium |