Synthesis of polyynes using dicobalt masking groups.

Extended triisopropylsilyl end-capped polyynes have been prepared from the corresponding tetracobalt complexes by removing the complexed dicobalt tetracarbonyldiphenylphosphinomethane (Co2(CO)4dppm) moieties. Unmasking of this 'masked alkyne equivalent' was achieved under mild conditions w...

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Váldodahkkit: Kohn, D, Gawel, P, Xiong, Y, Christensen, K, Anderson, H
Materiálatiipa: Journal article
Giella:English
Almmustuhtton: American Chemical Society 2018