NONUNIFORM ACCESSIBILITY AND THE USE OF HYDRODYNAMIC ELECTRODES FOR MECHANISTIC STUDIES - A COMPARISON OF WALL-JET AND ROTATING-DISK ELECTRODES

The merits of non-uniformly accessible electrodes for discriminating between electrode reaction mechanisms are established. In particular a comparison of the theoretical behaviour of the uniformly accessible rotating disc electrode and the highly non-uniformly accessible wall-jet electrode towards a...

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Päätekijät: Compton, R, Fisher, A, Tyley, G
Aineistotyyppi: Journal article
Kieli:English
Julkaistu: Kluwer Academic Publishers 1991
Kuvaus
Yhteenveto:The merits of non-uniformly accessible electrodes for discriminating between electrode reaction mechanisms are established. In particular a comparison of the theoretical behaviour of the uniformly accessible rotating disc electrode and the highly non-uniformly accessible wall-jet electrode towards a wide range of different types of electrode process shows that mechanistic resolution is better achieved with the latter electrode geometry. © 1991 Chapman and Hall Ltd.