NONUNIFORM ACCESSIBILITY AND THE USE OF HYDRODYNAMIC ELECTRODES FOR MECHANISTIC STUDIES - A COMPARISON OF WALL-JET AND ROTATING-DISK ELECTRODES
The merits of non-uniformly accessible electrodes for discriminating between electrode reaction mechanisms are established. In particular a comparison of the theoretical behaviour of the uniformly accessible rotating disc electrode and the highly non-uniformly accessible wall-jet electrode towards a...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
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Kluwer Academic Publishers
1991
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| Summary: | The merits of non-uniformly accessible electrodes for discriminating between electrode reaction mechanisms are established. In particular a comparison of the theoretical behaviour of the uniformly accessible rotating disc electrode and the highly non-uniformly accessible wall-jet electrode towards a wide range of different types of electrode process shows that mechanistic resolution is better achieved with the latter electrode geometry. © 1991 Chapman and Hall Ltd. |
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