Structural trends in ten-vertex endohedral clusters, M@E(10) and the synthesis of a new member of the family, [Fe@Sn10]3-.

The synthesis of a new endohedral ten-vertex Zintl ion cluster, [Fe@Sn10](3-), isoelectronic with [Fe@Ge10](3-), is reported. In an attempt to place this new cluster within the context of the known structural chemistry of the M@E10 family (M = transition metal, E = main group element), we have carri...

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Main Authors: Krämer, T, Duckworth, J, Ingram, MD, Zhou, B, McGrady, J, Goicoechea, J
格式: Journal article
语言:English
出版: 2013