Synthesis and reactivity of the 2-phosphaethynolate anion and phosphinecarboxamide
<p>This thesis describes a novel synthesis of the 2-phosphaethynolate anion, [PCO]<sup>–</sup>, via reaction of the [P<sub>7</sub>]<sup>3–</sup> Zintl cluster with carbon monoxide. The ligand properties of this fundamental molecule have been probed and compa...
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Format: | Thesis |
Published: |
2016
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