Synthesis and reactivity of the 2-phosphaethynolate anion and phosphinecarboxamide

<p>This thesis describes a novel synthesis of the 2-phosphaethynolate anion, [PCO]<sup>–</sup>, via reaction of the [P<sub>7</sub>]<sup>3–</sup> Zintl cluster with carbon monoxide. The ligand properties of this fundamental molecule have been probed and compa...

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Bibliographic Details
Main Author: Jupp, A
Other Authors: Goicoechea, J
Format: Thesis
Published: 2016