The absolute configuration of 1-epialexine hemihydrate.
The absolute and relative configurations of 1-epialexine are established by X-ray crystallographic analysis, giving (1S,2R,3R,7S,7aS)-1,2,7-trihydroxy-3-(hydroxymethyl)pyrrolizidine. The compound crystallizes as the hemihydrate C(8)H(15)NO(4) x 0.5H(2)O, with hydrogen bonds holding the water molecul...
| Main Authors: | , , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2008
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| _version_ | 1797096708935516160 |
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| author | Thompson, A Watkin, D Gal, Z Jones, L Hollinshead, J Jenkinson, S Fleet, G Nash, R |
| author_facet | Thompson, A Watkin, D Gal, Z Jones, L Hollinshead, J Jenkinson, S Fleet, G Nash, R |
| author_sort | Thompson, A |
| collection | OXFORD |
| description | The absolute and relative configurations of 1-epialexine are established by X-ray crystallographic analysis, giving (1S,2R,3R,7S,7aS)-1,2,7-trihydroxy-3-(hydroxymethyl)pyrrolizidine. The compound crystallizes as the hemihydrate C(8)H(15)NO(4) x 0.5H(2)O, with hydrogen bonds holding the water molecule in a hydrophilic pocket between epialexine bilayers. In addition, a comparison was made between results obtained from examination of the Bijvoet pairs from data sets collected using molybdenum and copper radiation. |
| first_indexed | 2024-03-07T04:45:24Z |
| format | Journal article |
| id | oxford-uuid:d3115f69-0b93-4f63-9dfc-b9a4d8e055ca |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T04:45:24Z |
| publishDate | 2008 |
| record_format | dspace |
| spelling | oxford-uuid:d3115f69-0b93-4f63-9dfc-b9a4d8e055ca2022-03-27T08:08:46ZThe absolute configuration of 1-epialexine hemihydrate.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:d3115f69-0b93-4f63-9dfc-b9a4d8e055caEnglishSymplectic Elements at Oxford2008Thompson, AWatkin, DGal, ZJones, LHollinshead, JJenkinson, SFleet, GNash, RThe absolute and relative configurations of 1-epialexine are established by X-ray crystallographic analysis, giving (1S,2R,3R,7S,7aS)-1,2,7-trihydroxy-3-(hydroxymethyl)pyrrolizidine. The compound crystallizes as the hemihydrate C(8)H(15)NO(4) x 0.5H(2)O, with hydrogen bonds holding the water molecule in a hydrophilic pocket between epialexine bilayers. In addition, a comparison was made between results obtained from examination of the Bijvoet pairs from data sets collected using molybdenum and copper radiation. |
| spellingShingle | Thompson, A Watkin, D Gal, Z Jones, L Hollinshead, J Jenkinson, S Fleet, G Nash, R The absolute configuration of 1-epialexine hemihydrate. |
| title | The absolute configuration of 1-epialexine hemihydrate. |
| title_full | The absolute configuration of 1-epialexine hemihydrate. |
| title_fullStr | The absolute configuration of 1-epialexine hemihydrate. |
| title_full_unstemmed | The absolute configuration of 1-epialexine hemihydrate. |
| title_short | The absolute configuration of 1-epialexine hemihydrate. |
| title_sort | absolute configuration of 1 epialexine hemihydrate |
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