A concise total synthesis of (+/-)-1-epiaustraline.
[reaction: see text] A concise total synthesis of 1-epiaustraline 3 is described that utilizes a diastereoselective Birch reduction of an electron-deficient pyrrole and a chelation-controlled vinyl Grignard addition to an aldehyde to introduce the C7 stereocenter. The C1 and C2 stereocenters were se...
| Main Authors: | , |
|---|---|
| פורמט: | Journal article |
| שפה: | English |
| יצא לאור: |
2004
|