A concise total synthesis of (+/-)-1-epiaustraline.
[reaction: see text] A concise total synthesis of 1-epiaustraline 3 is described that utilizes a diastereoselective Birch reduction of an electron-deficient pyrrole and a chelation-controlled vinyl Grignard addition to an aldehyde to introduce the C7 stereocenter. The C1 and C2 stereocenters were se...
| Main Authors: | , |
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| 格式: | Journal article |
| 語言: | English |
| 出版: |
2004
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