Iridium-catalyzed reductive allylation of esters

Iridium-catalyzed reductive allylation of esters

The catalytic reductive transformation of carboxylic esters into α-branched ethers is described. The procedure pivots on the chemoselective iridium-catalyzed hydrosilylation of ester and lactone functionality to afford a silyl acetal intermediate. Upon treatment with a Lewis acid, these hemilabile i...

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Номзүйн дэлгэрэнгүй
Үндсэн зохиолчид:	Xie, L, Rogers, J, Anastasiou, I, Leitch, J, Dixon, D
Формат:	Journal article
Хэл сонгох:	English
Хэвлэсэн:	American Chemical Society 2019

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