Copper(I) and silver(I) homometallic complexes of new bis(2,2′-bipyridine) ligands
New ligand systems containing two 2,2′-bipyridin-6-ylmethyl moieties linked via 1,4,10,13-tetraoxa-7,16-diazacyclooctadecane, 1,4,10,13-tetrathia-7,16-diazacyclooctadecane, 4,4′-bipyridinediium, N,N′,N″-tritosyldiethylenetriamine and toluene-p-sulfonamide spacer units have been prepared. A variety o...
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| Format: | Journal article |
| Language: | English |
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1992
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| _version_ | 1826298605331283968 |
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| author | Beer, P Wheeler, J Moore, C |
| author_facet | Beer, P Wheeler, J Moore, C |
| author_sort | Beer, P |
| collection | OXFORD |
| description | New ligand systems containing two 2,2′-bipyridin-6-ylmethyl moieties linked via 1,4,10,13-tetraoxa-7,16-diazacyclooctadecane, 1,4,10,13-tetrathia-7,16-diazacyclooctadecane, 4,4′-bipyridinediium, N,N′,N″-tritosyldiethylenetriamine and toluene-p-sulfonamide spacer units have been prepared. A variety of homometallic Copper(I) complexes have been isolated and fast atom bombardment mass spectrometry investigations suggest most of the complexes to be of general formula [Cu2L2][PF6]2. Solution 1H NMR spectra of these species imply the existence of additional complex components of 1:1 L:copper(I) ratio. A variety of mono- and bi-metallic silver(I) complexes were also isolated with these ligands. |
| first_indexed | 2024-03-07T04:49:25Z |
| format | Journal article |
| id | oxford-uuid:d473893f-c559-43c5-a0ab-763e56e7fc31 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T04:49:25Z |
| publishDate | 1992 |
| record_format | dspace |
| spelling | oxford-uuid:d473893f-c559-43c5-a0ab-763e56e7fc312022-03-27T08:18:31ZCopper(I) and silver(I) homometallic complexes of new bis(2,2′-bipyridine) ligandsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:d473893f-c559-43c5-a0ab-763e56e7fc31EnglishSymplectic Elements at Oxford1992Beer, PWheeler, JMoore, CNew ligand systems containing two 2,2′-bipyridin-6-ylmethyl moieties linked via 1,4,10,13-tetraoxa-7,16-diazacyclooctadecane, 1,4,10,13-tetrathia-7,16-diazacyclooctadecane, 4,4′-bipyridinediium, N,N′,N″-tritosyldiethylenetriamine and toluene-p-sulfonamide spacer units have been prepared. A variety of homometallic Copper(I) complexes have been isolated and fast atom bombardment mass spectrometry investigations suggest most of the complexes to be of general formula [Cu2L2][PF6]2. Solution 1H NMR spectra of these species imply the existence of additional complex components of 1:1 L:copper(I) ratio. A variety of mono- and bi-metallic silver(I) complexes were also isolated with these ligands. |
| spellingShingle | Beer, P Wheeler, J Moore, C Copper(I) and silver(I) homometallic complexes of new bis(2,2′-bipyridine) ligands |
| title | Copper(I) and silver(I) homometallic complexes of new bis(2,2′-bipyridine) ligands |
| title_full | Copper(I) and silver(I) homometallic complexes of new bis(2,2′-bipyridine) ligands |
| title_fullStr | Copper(I) and silver(I) homometallic complexes of new bis(2,2′-bipyridine) ligands |
| title_full_unstemmed | Copper(I) and silver(I) homometallic complexes of new bis(2,2′-bipyridine) ligands |
| title_short | Copper(I) and silver(I) homometallic complexes of new bis(2,2′-bipyridine) ligands |
| title_sort | copper i and silver i homometallic complexes of new bis 2 2 bipyridine ligands |
| work_keys_str_mv | AT beerp copperiandsilverihomometalliccomplexesofnewbis22bipyridineligands AT wheelerj copperiandsilverihomometalliccomplexesofnewbis22bipyridineligands AT moorec copperiandsilverihomometalliccomplexesofnewbis22bipyridineligands |