High-resolution x-ray spectroscopic study of the electronic structure of the prototypical p-type transparent conducting oxide CuAlO2

The electronic structure of the prototypical p-type transparent conducting oxide CuAlO2 has been studied by O K and Cu L3 shell x-ray absorption and emission and Al Kα excited valence photoemission and nonresonant Cu L3 emission spectra are dominated by the Cu 3d partial density of states. All three...

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Main Authors: Aston, D, Payne, D, Green, A, Egdell, R, Law, D, Guo, J, Glans, P, Learmonth, T, Smith, K
Format: Journal article
Language:English
Published: American Physical Society 2005
Subjects:
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author Aston, D
Payne, D
Green, A
Egdell, R
Law, D
Guo, J
Glans, P
Learmonth, T
Smith, K
author_facet Aston, D
Payne, D
Green, A
Egdell, R
Law, D
Guo, J
Glans, P
Learmonth, T
Smith, K
author_sort Aston, D
collection OXFORD
description The electronic structure of the prototypical p-type transparent conducting oxide CuAlO2 has been studied by O K and Cu L3 shell x-ray absorption and emission and Al Kα excited valence photoemission and nonresonant Cu L3 emission spectra are dominated by the Cu 3d partial density of states. All three techniques reveal mixing between O 2p and Cu 3d states. Cu L3 emission spectra excited just above the L3 threshold are dominated by inelastic scattering with 5.5 eV energy loss. This energy is shown to correspond to the separation between the dominant peaks in the filled and empty densities of states.
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spelling oxford-uuid:d5227cf2-c5a8-4027-8c5d-423c8e8505472022-03-27T08:23:50ZHigh-resolution x-ray spectroscopic study of the electronic structure of the prototypical p-type transparent conducting oxide CuAlO2Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:d5227cf2-c5a8-4027-8c5d-423c8e850547Chemistry & allied sciencesInorganic chemistryPhysicsEnglishOxford University Research Archive - ValetAmerican Physical Society2005Aston, DPayne, DGreen, AEgdell, RLaw, DGuo, JGlans, PLearmonth, TSmith, KThe electronic structure of the prototypical p-type transparent conducting oxide CuAlO2 has been studied by O K and Cu L3 shell x-ray absorption and emission and Al Kα excited valence photoemission and nonresonant Cu L3 emission spectra are dominated by the Cu 3d partial density of states. All three techniques reveal mixing between O 2p and Cu 3d states. Cu L3 emission spectra excited just above the L3 threshold are dominated by inelastic scattering with 5.5 eV energy loss. This energy is shown to correspond to the separation between the dominant peaks in the filled and empty densities of states.
spellingShingle Chemistry & allied sciences
Inorganic chemistry
Physics
Aston, D
Payne, D
Green, A
Egdell, R
Law, D
Guo, J
Glans, P
Learmonth, T
Smith, K
High-resolution x-ray spectroscopic study of the electronic structure of the prototypical p-type transparent conducting oxide CuAlO2
title High-resolution x-ray spectroscopic study of the electronic structure of the prototypical p-type transparent conducting oxide CuAlO2
title_full High-resolution x-ray spectroscopic study of the electronic structure of the prototypical p-type transparent conducting oxide CuAlO2
title_fullStr High-resolution x-ray spectroscopic study of the electronic structure of the prototypical p-type transparent conducting oxide CuAlO2
title_full_unstemmed High-resolution x-ray spectroscopic study of the electronic structure of the prototypical p-type transparent conducting oxide CuAlO2
title_short High-resolution x-ray spectroscopic study of the electronic structure of the prototypical p-type transparent conducting oxide CuAlO2
title_sort high resolution x ray spectroscopic study of the electronic structure of the prototypical p type transparent conducting oxide cualo2
topic Chemistry & allied sciences
Inorganic chemistry
Physics
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