Atomic structure and dynamics of epitaxial platinum bilayers on graphene
Platinum atomic layers grown on graphene were investigated by atomic resolution transmission electron microscopy (TEM). These TEM images reveal the epitaxial relationship between the atomically thin platinum layers and graphene, with two optimal epitaxies observed. The energetics of these epitaxies...
| Hoofdauteurs: | , , , , , , , , |
|---|---|
| Formaat: | Journal article |
| Taal: | English |
| Gepubliceerd in: |
American Chemical Society
2019
|
| Onderwerpen: |
| _version_ | 1826298756153212928 |
|---|---|
| author | Robertson, A Lee, G Lee, S Buntin, P Drexler, M Abdelhafiz, A Yoon, E Warner, J Alamgir, F |
| author_facet | Robertson, A Lee, G Lee, S Buntin, P Drexler, M Abdelhafiz, A Yoon, E Warner, J Alamgir, F |
| author_sort | Robertson, A |
| collection | OXFORD |
| description | Platinum atomic layers grown on graphene were investigated by atomic resolution transmission electron microscopy (TEM). These TEM images reveal the epitaxial relationship between the atomically thin platinum layers and graphene, with two optimal epitaxies observed. The energetics of these epitaxies influences the grain structure of the platinum film, facilitating grain growth via in-plane rotation and assimilation of neighbor grains, rather than grain coarsening from the movement of grain boundaries. This growth process was enabled due to the availability of several possible low-energy intermediate states for the rotating grains, the Pt-Gr epitaxies, which are minima in surface energy, and coincident site lattice grain boundaries, which are minima in grain boundary energy. Density functional theory calculations reveal a complex interplay of considerations for minimizing the platinum grain energy, with free platinum edges also having an effect on the relative energetics. We thus find that the platinum atomic layer grains undergo significant reorientation to minimize interface energy (via epitaxy), grain boundary energy (via low-energy orientations), and free edge energy. These results will be important for the design of two-dimensional graphene-supported platinum catalysts and obtaining large-area uniform platinum atomic layer films and also provide fundamental experimental insight into the growth of heteroepitaxial thin films. |
| first_indexed | 2024-03-07T04:51:40Z |
| format | Journal article |
| id | oxford-uuid:d52cfe6b-e22e-4cd6-8563-e992993c7ef3 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T04:51:40Z |
| publishDate | 2019 |
| publisher | American Chemical Society |
| record_format | dspace |
| spelling | oxford-uuid:d52cfe6b-e22e-4cd6-8563-e992993c7ef32022-03-27T08:24:16ZAtomic structure and dynamics of epitaxial platinum bilayers on grapheneJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:d52cfe6b-e22e-4cd6-8563-e992993c7ef3Grain boundaries EpitaxyPlatinumGrainTwo dimensional materialsEnglishSymplectic Elements at OxfordAmerican Chemical Society2019Robertson, ALee, GLee, SBuntin, PDrexler, MAbdelhafiz, AYoon, EWarner, JAlamgir, FPlatinum atomic layers grown on graphene were investigated by atomic resolution transmission electron microscopy (TEM). These TEM images reveal the epitaxial relationship between the atomically thin platinum layers and graphene, with two optimal epitaxies observed. The energetics of these epitaxies influences the grain structure of the platinum film, facilitating grain growth via in-plane rotation and assimilation of neighbor grains, rather than grain coarsening from the movement of grain boundaries. This growth process was enabled due to the availability of several possible low-energy intermediate states for the rotating grains, the Pt-Gr epitaxies, which are minima in surface energy, and coincident site lattice grain boundaries, which are minima in grain boundary energy. Density functional theory calculations reveal a complex interplay of considerations for minimizing the platinum grain energy, with free platinum edges also having an effect on the relative energetics. We thus find that the platinum atomic layer grains undergo significant reorientation to minimize interface energy (via epitaxy), grain boundary energy (via low-energy orientations), and free edge energy. These results will be important for the design of two-dimensional graphene-supported platinum catalysts and obtaining large-area uniform platinum atomic layer films and also provide fundamental experimental insight into the growth of heteroepitaxial thin films. |
| spellingShingle | Grain boundaries Epitaxy Platinum Grain Two dimensional materials Robertson, A Lee, G Lee, S Buntin, P Drexler, M Abdelhafiz, A Yoon, E Warner, J Alamgir, F Atomic structure and dynamics of epitaxial platinum bilayers on graphene |
| title | Atomic structure and dynamics of epitaxial platinum bilayers on graphene |
| title_full | Atomic structure and dynamics of epitaxial platinum bilayers on graphene |
| title_fullStr | Atomic structure and dynamics of epitaxial platinum bilayers on graphene |
| title_full_unstemmed | Atomic structure and dynamics of epitaxial platinum bilayers on graphene |
| title_short | Atomic structure and dynamics of epitaxial platinum bilayers on graphene |
| title_sort | atomic structure and dynamics of epitaxial platinum bilayers on graphene |
| topic | Grain boundaries Epitaxy Platinum Grain Two dimensional materials |
| work_keys_str_mv | AT robertsona atomicstructureanddynamicsofepitaxialplatinumbilayersongraphene AT leeg atomicstructureanddynamicsofepitaxialplatinumbilayersongraphene AT lees atomicstructureanddynamicsofepitaxialplatinumbilayersongraphene AT buntinp atomicstructureanddynamicsofepitaxialplatinumbilayersongraphene AT drexlerm atomicstructureanddynamicsofepitaxialplatinumbilayersongraphene AT abdelhafiza atomicstructureanddynamicsofepitaxialplatinumbilayersongraphene AT yoone atomicstructureanddynamicsofepitaxialplatinumbilayersongraphene AT warnerj atomicstructureanddynamicsofepitaxialplatinumbilayersongraphene AT alamgirf atomicstructureanddynamicsofepitaxialplatinumbilayersongraphene |