Transition metal imide organic imine metathesis reactions: unexpected observations
Mixtures of [Ti(NBut)Cl2(py)3] 1 and PhC(NAr)H (Ar = C6H3Me2-2,6 or C6H4Me-4) gave quantitative conversion to [Ti(NAr)Cl2(py)3] and PhC(NBut)H, the products of Ti=N-But/C=NAr transition metal imide/organic imine metathesis; examination of the kinetics for Ar = C6H4Me-4 showed that the rate limiting...
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| Format: | Journal article |
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1998
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| _version_ | 1797097442525577216 |
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| author | McInnes, J Mountford, P |
| author_facet | McInnes, J Mountford, P |
| author_sort | McInnes, J |
| collection | OXFORD |
| description | Mixtures of [Ti(NBut)Cl2(py)3] 1 and PhC(NAr)H (Ar = C6H3Me2-2,6 or C6H4Me-4) gave quantitative conversion to [Ti(NAr)Cl2(py)3] and PhC(NBut)H, the products of Ti=N-But/C=NAr transition metal imide/organic imine metathesis; examination of the kinetics for Ar = C6H4Me-4 showed that the rate limiting step for this process is zero order in [1], demonstrating that these reactions do not involve metal imide particiption in the rate limiting step. |
| first_indexed | 2024-03-07T04:55:34Z |
| format | Journal article |
| id | oxford-uuid:d67d1ec2-79f9-45ed-9f32-167db45c0871 |
| institution | University of Oxford |
| last_indexed | 2024-03-07T04:55:34Z |
| publishDate | 1998 |
| record_format | dspace |
| spelling | oxford-uuid:d67d1ec2-79f9-45ed-9f32-167db45c08712022-03-27T08:33:52ZTransition metal imide organic imine metathesis reactions: unexpected observationsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:d67d1ec2-79f9-45ed-9f32-167db45c0871Symplectic Elements at Oxford1998McInnes, JMountford, PMixtures of [Ti(NBut)Cl2(py)3] 1 and PhC(NAr)H (Ar = C6H3Me2-2,6 or C6H4Me-4) gave quantitative conversion to [Ti(NAr)Cl2(py)3] and PhC(NBut)H, the products of Ti=N-But/C=NAr transition metal imide/organic imine metathesis; examination of the kinetics for Ar = C6H4Me-4 showed that the rate limiting step for this process is zero order in [1], demonstrating that these reactions do not involve metal imide particiption in the rate limiting step. |
| spellingShingle | McInnes, J Mountford, P Transition metal imide organic imine metathesis reactions: unexpected observations |
| title | Transition metal imide organic imine metathesis reactions: unexpected observations |
| title_full | Transition metal imide organic imine metathesis reactions: unexpected observations |
| title_fullStr | Transition metal imide organic imine metathesis reactions: unexpected observations |
| title_full_unstemmed | Transition metal imide organic imine metathesis reactions: unexpected observations |
| title_short | Transition metal imide organic imine metathesis reactions: unexpected observations |
| title_sort | transition metal imide organic imine metathesis reactions unexpected observations |
| work_keys_str_mv | AT mcinnesj transitionmetalimideorganiciminemetathesisreactionsunexpectedobservations AT mountfordp transitionmetalimideorganiciminemetathesisreactionsunexpectedobservations |