The hydride anion in an extended transition metal oxide array: LaSrCoO3H0.7.

The hydride anion in an extended transition metal oxide array: LaSrCoO3H0.7.

We present the synthesis and structural characterization of a transition metal oxide hydride, LaSrCoO3H0.7, which adopts an unprecedented structure in which oxide chains are bridged by hydride anions to form a two-dimensional extended network. The metal centers are strongly coupled by their bonding...

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Dades bibliogràfiques
Autors principals: Hayward, M, Cussen, E, Claridge, J, Bieringer, M, Rosseinsky, M, Kiely, C, Blundell, S, Marshall, I, Pratt, F
Format: Journal article
Idioma:English
Publicat: 2002
Descripció
Sumari:We present the synthesis and structural characterization of a transition metal oxide hydride, LaSrCoO3H0.7, which adopts an unprecedented structure in which oxide chains are bridged by hydride anions to form a two-dimensional extended network. The metal centers are strongly coupled by their bonding with both oxide and hydride ligands to produce magnetic ordering at temperatures up to at least 350 kelvin. The synthetic route is sufficiently general to allow the prediction of a new class of transition metal--containing electronic and magnetic materials.

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