The hydride anion in an extended transition metal oxide array: LaSrCoO3H0.7.
We present the synthesis and structural characterization of a transition metal oxide hydride, LaSrCoO3H0.7, which adopts an unprecedented structure in which oxide chains are bridged by hydride anions to form a two-dimensional extended network. The metal centers are strongly coupled by their bonding...
| Main Authors: | , , , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2002
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| _version_ | 1826299063912366080 |
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| author | Hayward, M Cussen, E Claridge, J Bieringer, M Rosseinsky, M Kiely, C Blundell, S Marshall, I Pratt, F |
| author_facet | Hayward, M Cussen, E Claridge, J Bieringer, M Rosseinsky, M Kiely, C Blundell, S Marshall, I Pratt, F |
| author_sort | Hayward, M |
| collection | OXFORD |
| description | We present the synthesis and structural characterization of a transition metal oxide hydride, LaSrCoO3H0.7, which adopts an unprecedented structure in which oxide chains are bridged by hydride anions to form a two-dimensional extended network. The metal centers are strongly coupled by their bonding with both oxide and hydride ligands to produce magnetic ordering at temperatures up to at least 350 kelvin. The synthetic route is sufficiently general to allow the prediction of a new class of transition metal--containing electronic and magnetic materials. |
| first_indexed | 2024-03-07T04:56:13Z |
| format | Journal article |
| id | oxford-uuid:d6aff032-b51c-40fd-8455-233975150ede |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T04:56:13Z |
| publishDate | 2002 |
| record_format | dspace |
| spelling | oxford-uuid:d6aff032-b51c-40fd-8455-233975150ede2022-03-27T08:35:28ZThe hydride anion in an extended transition metal oxide array: LaSrCoO3H0.7.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:d6aff032-b51c-40fd-8455-233975150edeEnglishSymplectic Elements at Oxford2002Hayward, MCussen, EClaridge, JBieringer, MRosseinsky, MKiely, CBlundell, SMarshall, IPratt, FWe present the synthesis and structural characterization of a transition metal oxide hydride, LaSrCoO3H0.7, which adopts an unprecedented structure in which oxide chains are bridged by hydride anions to form a two-dimensional extended network. The metal centers are strongly coupled by their bonding with both oxide and hydride ligands to produce magnetic ordering at temperatures up to at least 350 kelvin. The synthetic route is sufficiently general to allow the prediction of a new class of transition metal--containing electronic and magnetic materials. |
| spellingShingle | Hayward, M Cussen, E Claridge, J Bieringer, M Rosseinsky, M Kiely, C Blundell, S Marshall, I Pratt, F The hydride anion in an extended transition metal oxide array: LaSrCoO3H0.7. |
| title | The hydride anion in an extended transition metal oxide array: LaSrCoO3H0.7. |
| title_full | The hydride anion in an extended transition metal oxide array: LaSrCoO3H0.7. |
| title_fullStr | The hydride anion in an extended transition metal oxide array: LaSrCoO3H0.7. |
| title_full_unstemmed | The hydride anion in an extended transition metal oxide array: LaSrCoO3H0.7. |
| title_short | The hydride anion in an extended transition metal oxide array: LaSrCoO3H0.7. |
| title_sort | hydride anion in an extended transition metal oxide array lasrcoo3h0 7 |
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