Rhodium(I) catalysis for intermolecular alkyne hydroacylation and desymmetrisation

Rhodium(I) catalysis for intermolecular alkyne hydroacylation and desymmetrisation

<p>This thesis discloses the uses and development of rhodium(I) catalysis within intermolecular hydroacylation and asymmetric [2+2+2] cycloadditions.</p> <p><b>Chapter 1</b> provides a general overview of the key methods and tethering strategies within the field rhodiu...

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Bibliografiske detaljer
Hovedforfatter:	Moseley, D
Andre forfattere:	Willis, M
Format:	Thesis
Sprog:	English
Udgivet:	2022
Fag:	Chemistry, Organic Synthesis

Lignende værker

Tandem catalytic processes involving Rhodium-catalysed intermolecular hydroacylation
af: Lenden, P
Udgivet: (2011)

Mechanistic studies of rhodium-catalysed intermolecular hydroacylation
af: Barwick-Silk, J
Udgivet: (2018)

Rhodium catalysed hydroacylation reactions in the synthesis of heterocycles
af: Ylioja, P
Udgivet: (2011)

Controlling selectivity in the rhodium-catalysed intermolecular hydroacylation reaction
af: Pawley, R
Udgivet: (2012)

Exploring and exploiting selectivity in Rhodium-catalysed hydroacylation reactions
af: Poingdestre, SJ
Udgivet: (2012)

Traceless chelation-controlled rhodium-catalyzed intermolecular alkene and alkyne hydroacylation.
af: Hooper, J, et al.
Udgivet: (2013)

New applications of rhodium-catalysed hydroacylation
af: Iwumene, NUN
Udgivet: (2022)

Rhodium (I) catalyzed intermolecular hydroacylation.
af: Sapmaz, S, et al.
Udgivet: (2001)

Exploiting carbonyl groups to control intermolecular rhodium-catalyzed alkene and alkyne hydroacylation
af: Coxon, TJ, et al.
Udgivet: (2017)

Exploring small bite-angle PNP and PCP ligands for the rhodium-catalysed intermolecular hydroacylation of b-s-substituted aldehydes with alkenes and alkynes
af: Pernik, I
Udgivet: (2014)

Applications of rhodium-catalysed hydroacylation in heterocycle synthesis
af: Majhail, M
Udgivet: (2016)

α‐Amidoaldehydes as substrates in rhodium‐catalyzed intermolecular alkyne hydroacylation: The synthesis of α‐Amidoketones
af: Pal, R, et al.
Udgivet: (2020)

a-Amidoaldehydes as substrates in rhodium-catalyzed intermolecular alkyne hydroacylation: The synthesis of a-amidoketones
af: Pal, R, et al.
Udgivet: (2020)

New reactivity and selectivity in rhodium-catalysed hydroacylation
af: Pal, R
Udgivet: (2020)

O-substituted alkyl aldehydes for rhodium-catalyzed intermolecular alkyne hydroacylation: the utility of methylthiomethyl ethers.
af: Parsons, SR, et al.
Udgivet: (2011)

Rhodium-catalysed linear-selective alkyne hydroacylation.
af: Poingdestre, S, et al.
Udgivet: (2012)

Rhodium-catalyzed enantioselective intermolecular hydroacylation reactions
af: Gonzalez-Rodriguez, C, et al.
Udgivet: (2011)

Replacing dichloroethane as a solvent for rhodium-catalysed intermolecular alkyne hydroacylation reactions: the utility of propylene carbonate
af: Lenden, P, et al.
Udgivet: (2011)

Rhodium-catalysed intermolecular alkyne hydroacylation: the enantioselective synthesis of α- and β-substituted ketones by kinetic resolution.
af: González-Rodríguez, C, et al.
Udgivet: (2010)

An enamine controlling group for rhodium-catalyzed intermolecular hydroacylation
af: Straker, R, et al.
Udgivet: (2018)

Rhodium-catalyzed intermolecular chelation controlled alkene and alkyne hydroacylation: synthetic scope of beta-S-substituted aldehyde substrates.
af: Willis, M, et al.
Udgivet: (2006)

Azine N-oxides as effective controlling groups for Rh-catalysed intermolecular alkyne hydroacylation
af: Moseley, DF, et al.
Udgivet: (2021)

Diversely substituted quinolines via rhodium-catalyzed alkyne hydroacylation
af: Willis, M, et al.
Udgivet: (2016)

Ketone synthesis via rhodium-catalyzed traceless chelation-controlled hydroacylation reactions
af: Gao, M
Udgivet: (2018)

Cobalt-catalyzed intermolecular hydroacylation of olefins through chelation-assisted imidoyl C-H activation
af: Yang, Junfeng, et al.
Udgivet: (2015)

Sequential catalysis: Exploiting a single rhodium(I) catalyst to promote an alkyne hydroacylation–aryl boronic acid conjugate addition sequence
af: Fernández, M, et al.
Udgivet: (2016)

Chelation-controlled intermolecular alkene and alkyne hydroacylation: the utility of beta-thioacetal aldehydes.
af: Willis, M, et al.
Udgivet: (2005)

Enantioselective desymmetrisation towards the synthesis of daphniphyllum alkaloids
af: Ellis, SR
Udgivet: (2019)

2-Aminobenzaldehydes as versatile substrates for rhodium-catalyzed alkyne hydroacylation: application to dihydroquinolone synthesis.
af: Castaing, M, et al.
Udgivet: (2013)

Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch.
af: González-Rodríguez, C, et al.
Udgivet: (2011)

Intermolecular rhodium catalyzed hydroacylation of allenes: the regioselective synthesis of beta,gamma-unsaturated ketones
af: Randell-Sly, H, et al.
Udgivet: (2009)

Intermolecular hydroacylation: high activity rhodium catalysts containing small-bite-angle diphosphine ligands.
af: Chaplin, AB, et al.
Udgivet: (2012)

Intermolecular Alkyne Hydroacylation. Mechanistic Insight from the Isolation of the Vinyl Intermediate That Precedes Reductive Elimination
af: Pawley, R, et al.
Udgivet: (2012)

Hydroacylation of Alkenes, Alkynes, and Allenes
af: Willis, M
Udgivet: (2014)

Abnormal N-heterocyclic carbene gold(I) complexes : synthesis, structure, and catalysis in hydration of alkynes
af: Xu, Xiangya, et al.
Udgivet: (2013)

Cobalt-catalyzed arylzincation of alkynes and alkenes involving 1,4-cobalt migration
af: Tan, Boon Hong
Udgivet: (2015)

Catalytic enantioselective intermolecular hydroacylation: rhodium-catalyzed combination of beta-S-aldehydes and 1,3-disubstituted allenes.
af: Osborne, J, et al.
Udgivet: (2008)

Transition metal catalysis in the presence of fluorinating reagents
af: Hopkinson, M
Udgivet: (2011)

Oxidant free rhodium-catalyzed C-C bond formation via C-H bond activation
af: Feng, Daming
Udgivet: (2016)

The reaction of [Cp*RhCl2]2, aniline, and a terminal alkyne : formation of cyclometalated rhodium(III) complexes
af: Kumaran, Elumalai, et al.
Udgivet: (2014)