Rhodium(I) catalysis for intermolecular alkyne hydroacylation and desymmetrisation

Rhodium(I) catalysis for intermolecular alkyne hydroacylation and desymmetrisation

<p>This thesis discloses the uses and development of rhodium(I) catalysis within intermolecular hydroacylation and asymmetric [2+2+2] cycloadditions.</p> <p><b>Chapter 1</b> provides a general overview of the key methods and tethering strategies within the field rhodiu...

Бүрэн тодорхойлолт

Номзүйн дэлгэрэнгүй
Үндсэн зохиолч:	Moseley, D
Бусад зохиолчид:	Willis, M
Формат:	Дипломын ажил
Хэл сонгох:	English
Хэвлэсэн:	2022
Нөхцлүүд:	Chemistry, Organic Synthesis

Ижил төстэй зүйлс

Tandem catalytic processes involving Rhodium-catalysed intermolecular hydroacylation
-н: Lenden, P
Хэвлэсэн: (2011)

Mechanistic studies of rhodium-catalysed intermolecular hydroacylation
-н: Barwick-Silk, J
Хэвлэсэн: (2018)

Rhodium catalysed hydroacylation reactions in the synthesis of heterocycles
-н: Ylioja, P
Хэвлэсэн: (2011)

Controlling selectivity in the rhodium-catalysed intermolecular hydroacylation reaction
-н: Pawley, R
Хэвлэсэн: (2012)

Exploring and exploiting selectivity in Rhodium-catalysed hydroacylation reactions
-н: Poingdestre, SJ
Хэвлэсэн: (2012)

Traceless chelation-controlled rhodium-catalyzed intermolecular alkene and alkyne hydroacylation.
-н: Hooper, J, зэрэг
Хэвлэсэн: (2013)

New applications of rhodium-catalysed hydroacylation
-н: Iwumene, NUN
Хэвлэсэн: (2022)

Rhodium (I) catalyzed intermolecular hydroacylation.
-н: Sapmaz, S, зэрэг
Хэвлэсэн: (2001)

Exploiting carbonyl groups to control intermolecular rhodium-catalyzed alkene and alkyne hydroacylation
-н: Coxon, TJ, зэрэг
Хэвлэсэн: (2017)

Exploring small bite-angle PNP and PCP ligands for the rhodium-catalysed intermolecular hydroacylation of b-s-substituted aldehydes with alkenes and alkynes
-н: Pernik, I
Хэвлэсэн: (2014)

Applications of rhodium-catalysed hydroacylation in heterocycle synthesis
-н: Majhail, M
Хэвлэсэн: (2016)

α‐Amidoaldehydes as substrates in rhodium‐catalyzed intermolecular alkyne hydroacylation: The synthesis of α‐Amidoketones
-н: Pal, R, зэрэг
Хэвлэсэн: (2020)

a-Amidoaldehydes as substrates in rhodium-catalyzed intermolecular alkyne hydroacylation: The synthesis of a-amidoketones
-н: Pal, R, зэрэг
Хэвлэсэн: (2020)

New reactivity and selectivity in rhodium-catalysed hydroacylation
-н: Pal, R
Хэвлэсэн: (2020)

O-substituted alkyl aldehydes for rhodium-catalyzed intermolecular alkyne hydroacylation: the utility of methylthiomethyl ethers.
-н: Parsons, SR, зэрэг
Хэвлэсэн: (2011)

Rhodium-catalysed linear-selective alkyne hydroacylation.
-н: Poingdestre, S, зэрэг
Хэвлэсэн: (2012)

Rhodium-catalyzed enantioselective intermolecular hydroacylation reactions
-н: Gonzalez-Rodriguez, C, зэрэг
Хэвлэсэн: (2011)

Replacing dichloroethane as a solvent for rhodium-catalysed intermolecular alkyne hydroacylation reactions: the utility of propylene carbonate
-н: Lenden, P, зэрэг
Хэвлэсэн: (2011)

Rhodium-catalysed intermolecular alkyne hydroacylation: the enantioselective synthesis of α- and β-substituted ketones by kinetic resolution.
-н: González-Rodríguez, C, зэрэг
Хэвлэсэн: (2010)

An enamine controlling group for rhodium-catalyzed intermolecular hydroacylation
-н: Straker, R, зэрэг
Хэвлэсэн: (2018)

Rhodium-catalyzed intermolecular chelation controlled alkene and alkyne hydroacylation: synthetic scope of beta-S-substituted aldehyde substrates.
-н: Willis, M, зэрэг
Хэвлэсэн: (2006)

Azine N-oxides as effective controlling groups for Rh-catalysed intermolecular alkyne hydroacylation
-н: Moseley, DF, зэрэг
Хэвлэсэн: (2021)

Diversely substituted quinolines via rhodium-catalyzed alkyne hydroacylation
-н: Willis, M, зэрэг
Хэвлэсэн: (2016)

Ketone synthesis via rhodium-catalyzed traceless chelation-controlled hydroacylation reactions
-н: Gao, M
Хэвлэсэн: (2018)

Cobalt-catalyzed intermolecular hydroacylation of olefins through chelation-assisted imidoyl C-H activation
-н: Yang, Junfeng, зэрэг
Хэвлэсэн: (2015)

Sequential catalysis: Exploiting a single rhodium(I) catalyst to promote an alkyne hydroacylation–aryl boronic acid conjugate addition sequence
-н: Fernández, M, зэрэг
Хэвлэсэн: (2016)

Chelation-controlled intermolecular alkene and alkyne hydroacylation: the utility of beta-thioacetal aldehydes.
-н: Willis, M, зэрэг
Хэвлэсэн: (2005)

Enantioselective desymmetrisation towards the synthesis of daphniphyllum alkaloids
-н: Ellis, SR
Хэвлэсэн: (2019)

2-Aminobenzaldehydes as versatile substrates for rhodium-catalyzed alkyne hydroacylation: application to dihydroquinolone synthesis.
-н: Castaing, M, зэрэг
Хэвлэсэн: (2013)

Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch.
-н: González-Rodríguez, C, зэрэг
Хэвлэсэн: (2011)

Intermolecular rhodium catalyzed hydroacylation of allenes: the regioselective synthesis of beta,gamma-unsaturated ketones
-н: Randell-Sly, H, зэрэг
Хэвлэсэн: (2009)

Intermolecular hydroacylation: high activity rhodium catalysts containing small-bite-angle diphosphine ligands.
-н: Chaplin, AB, зэрэг
Хэвлэсэн: (2012)

Intermolecular Alkyne Hydroacylation. Mechanistic Insight from the Isolation of the Vinyl Intermediate That Precedes Reductive Elimination
-н: Pawley, R, зэрэг
Хэвлэсэн: (2012)

Hydroacylation of Alkenes, Alkynes, and Allenes
-н: Willis, M
Хэвлэсэн: (2014)

Abnormal N-heterocyclic carbene gold(I) complexes : synthesis, structure, and catalysis in hydration of alkynes
-н: Xu, Xiangya, зэрэг
Хэвлэсэн: (2013)

Cobalt-catalyzed arylzincation of alkynes and alkenes involving 1,4-cobalt migration
-н: Tan, Boon Hong
Хэвлэсэн: (2015)

Catalytic enantioselective intermolecular hydroacylation: rhodium-catalyzed combination of beta-S-aldehydes and 1,3-disubstituted allenes.
-н: Osborne, J, зэрэг
Хэвлэсэн: (2008)

Transition metal catalysis in the presence of fluorinating reagents
-н: Hopkinson, M
Хэвлэсэн: (2011)

Oxidant free rhodium-catalyzed C-C bond formation via C-H bond activation
-н: Feng, Daming
Хэвлэсэн: (2016)

The reaction of [Cp*RhCl2]2, aniline, and a terminal alkyne : formation of cyclometalated rhodium(III) complexes
-н: Kumaran, Elumalai, зэрэг
Хэвлэсэн: (2014)