Rhodium(I) catalysis for intermolecular alkyne hydroacylation and desymmetrisation

Rhodium(I) catalysis for intermolecular alkyne hydroacylation and desymmetrisation

<p>This thesis discloses the uses and development of rhodium(I) catalysis within intermolecular hydroacylation and asymmetric [2+2+2] cycloadditions.</p> <p><b>Chapter 1</b> provides a general overview of the key methods and tethering strategies within the field rhodiu...

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Chi tiết về thư mục
Tác giả chính:	Moseley, D
Tác giả khác:	Willis, M
Định dạng:	Luận văn
Ngôn ngữ:	English
Được phát hành:	2022
Những chủ đề:	Chemistry, Organic Synthesis

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Traceless chelation-controlled rhodium-catalyzed intermolecular alkene and alkyne hydroacylation.
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Rhodium-catalyzed intermolecular chelation controlled alkene and alkyne hydroacylation: synthetic scope of beta-S-substituted aldehyde substrates.
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Azine N-oxides as effective controlling groups for Rh-catalysed intermolecular alkyne hydroacylation
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Enantioselective desymmetrisation towards the synthesis of daphniphyllum alkaloids
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Hydroacylation of Alkenes, Alkynes, and Allenes
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Transition metal catalysis in the presence of fluorinating reagents
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Oxidant free rhodium-catalyzed C-C bond formation via C-H bond activation
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The reaction of [Cp*RhCl2]2, aniline, and a terminal alkyne : formation of cyclometalated rhodium(III) complexes
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