(C3H12N2)(2)[UO2(H2O)(2)(SO4)(2)](2)center dot 2H(2)O: an organically templated uranium sulfate with a novel dimer type
The title compound, bis(propane-1,2-diaminium) tetraaquadi-μ 2-sulfato-disulfatotetraoxodiuranate(VI) dihydrate, (C 3H12N2)2[U2O 4(SO4)4(H2O) 4]·2H2O, contains discrete centrosymmetric anionic {[UO2(H2O)2(SO4)2] 2}4- dimers with C3H12N 22+ cations balancing the charge. The dimers form hydrogen-bonde...
| Главные авторы: | , , |
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| Формат: | Journal article |
| Язык: | English |
| Опубликовано: |
2005
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| _version_ | 1826299117495648256 |
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| author | Doran, M Norquist, A O'Hare, D |
| author_facet | Doran, M Norquist, A O'Hare, D |
| author_sort | Doran, M |
| collection | OXFORD |
| description | The title compound, bis(propane-1,2-diaminium) tetraaquadi-μ 2-sulfato-disulfatotetraoxodiuranate(VI) dihydrate, (C 3H12N2)2[U2O 4(SO4)4(H2O) 4]·2H2O, contains discrete centrosymmetric anionic {[UO2(H2O)2(SO4)2] 2}4- dimers with C3H12N 22+ cations balancing the charge. The dimers form hydrogen-bonded layers. The cations and occluded water molecules participate in an extensive hydrogen-bonding network. Each UVI centre is seven-coordinate with a pentagonal-bipyramidal geometry. Both pendent and bridging sulfate tetrahedra are observed, as well as bound and occluded water molecules. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved. |
| first_indexed | 2024-03-07T04:57:02Z |
| format | Journal article |
| id | oxford-uuid:d6f662b5-d5ad-4118-9a4f-9c3c97b83f30 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T04:57:02Z |
| publishDate | 2005 |
| record_format | dspace |
| spelling | oxford-uuid:d6f662b5-d5ad-4118-9a4f-9c3c97b83f302022-03-27T08:37:26Z(C3H12N2)(2)[UO2(H2O)(2)(SO4)(2)](2)center dot 2H(2)O: an organically templated uranium sulfate with a novel dimer typeJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:d6f662b5-d5ad-4118-9a4f-9c3c97b83f30EnglishSymplectic Elements at Oxford2005Doran, MNorquist, AO'Hare, DThe title compound, bis(propane-1,2-diaminium) tetraaquadi-μ 2-sulfato-disulfatotetraoxodiuranate(VI) dihydrate, (C 3H12N2)2[U2O 4(SO4)4(H2O) 4]·2H2O, contains discrete centrosymmetric anionic {[UO2(H2O)2(SO4)2] 2}4- dimers with C3H12N 22+ cations balancing the charge. The dimers form hydrogen-bonded layers. The cations and occluded water molecules participate in an extensive hydrogen-bonding network. Each UVI centre is seven-coordinate with a pentagonal-bipyramidal geometry. Both pendent and bridging sulfate tetrahedra are observed, as well as bound and occluded water molecules. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved. |
| spellingShingle | Doran, M Norquist, A O'Hare, D (C3H12N2)(2)[UO2(H2O)(2)(SO4)(2)](2)center dot 2H(2)O: an organically templated uranium sulfate with a novel dimer type |
| title | (C3H12N2)(2)[UO2(H2O)(2)(SO4)(2)](2)center dot 2H(2)O: an organically templated uranium sulfate with a novel dimer type |
| title_full | (C3H12N2)(2)[UO2(H2O)(2)(SO4)(2)](2)center dot 2H(2)O: an organically templated uranium sulfate with a novel dimer type |
| title_fullStr | (C3H12N2)(2)[UO2(H2O)(2)(SO4)(2)](2)center dot 2H(2)O: an organically templated uranium sulfate with a novel dimer type |
| title_full_unstemmed | (C3H12N2)(2)[UO2(H2O)(2)(SO4)(2)](2)center dot 2H(2)O: an organically templated uranium sulfate with a novel dimer type |
| title_short | (C3H12N2)(2)[UO2(H2O)(2)(SO4)(2)](2)center dot 2H(2)O: an organically templated uranium sulfate with a novel dimer type |
| title_sort | c3h12n2 2 uo2 h2o 2 so4 2 2 center dot 2h 2 o an organically templated uranium sulfate with a novel dimer type |
| work_keys_str_mv | AT doranm c3h12n22uo2h2o2so422centerdot2h2oanorganicallytemplateduraniumsulfatewithanoveldimertype AT norquista c3h12n22uo2h2o2so422centerdot2h2oanorganicallytemplateduraniumsulfatewithanoveldimertype AT ohared c3h12n22uo2h2o2so422centerdot2h2oanorganicallytemplateduraniumsulfatewithanoveldimertype |