(6S)-Methyl-L-swainsonine [(1R, 2S, 6S, 8S, 8aS)-6-methyloctahydroindolizine-1,2,8-triol]
(6S)-Methyl-L-swainsonine, C 9H 17NO 3, together with the 6R-epimer, was formed in a synthetic sequence in which there was an ambiguity in configuration at position C-6. This ambiguity was resolved by establishing the relative s...
Main Authors: | , , , |
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Format: | Journal article |
Language: | English |
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2007
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_version_ | 1797097649953832960 |
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author | Hakansson, A Horne, G Fleet, G Watkin, D |
author_facet | Hakansson, A Horne, G Fleet, G Watkin, D |
author_sort | Hakansson, A |
collection | OXFORD |
description | (6S)-Methyl-L-swainsonine, C 9H 17NO 3, together with the 6R-epimer, was formed in a synthetic sequence in which there was an ambiguity in configuration at position C-6. This ambiguity was resolved by establishing the relative stereochemistry of the title compound by X-ray crystallographic analysis. The absolute configuration was determined by the use of D-glycero-D-gulo-heptono-1,4-lactone as the starting material. © 2007 International Union of Crystallography. All rights reserved. |
first_indexed | 2024-03-07T04:58:30Z |
format | Journal article |
id | oxford-uuid:d771025e-ecc8-478c-8581-198d6c562cf7 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-07T04:58:30Z |
publishDate | 2007 |
record_format | dspace |
spelling | oxford-uuid:d771025e-ecc8-478c-8581-198d6c562cf72022-03-27T08:41:05Z(6S)-Methyl-L-swainsonine [(1R, 2S, 6S, 8S, 8aS)-6-methyloctahydroindolizine-1,2,8-triol]Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:d771025e-ecc8-478c-8581-198d6c562cf7EnglishSymplectic Elements at Oxford2007Hakansson, AHorne, GFleet, GWatkin, D(6S)-Methyl-L-swainsonine, C 9H 17NO 3, together with the 6R-epimer, was formed in a synthetic sequence in which there was an ambiguity in configuration at position C-6. This ambiguity was resolved by establishing the relative stereochemistry of the title compound by X-ray crystallographic analysis. The absolute configuration was determined by the use of D-glycero-D-gulo-heptono-1,4-lactone as the starting material. © 2007 International Union of Crystallography. All rights reserved. |
spellingShingle | Hakansson, A Horne, G Fleet, G Watkin, D (6S)-Methyl-L-swainsonine [(1R, 2S, 6S, 8S, 8aS)-6-methyloctahydroindolizine-1,2,8-triol] |
title | (6S)-Methyl-L-swainsonine [(1R, 2S, 6S, 8S, 8aS)-6-methyloctahydroindolizine-1,2,8-triol] |
title_full | (6S)-Methyl-L-swainsonine [(1R, 2S, 6S, 8S, 8aS)-6-methyloctahydroindolizine-1,2,8-triol] |
title_fullStr | (6S)-Methyl-L-swainsonine [(1R, 2S, 6S, 8S, 8aS)-6-methyloctahydroindolizine-1,2,8-triol] |
title_full_unstemmed | (6S)-Methyl-L-swainsonine [(1R, 2S, 6S, 8S, 8aS)-6-methyloctahydroindolizine-1,2,8-triol] |
title_short | (6S)-Methyl-L-swainsonine [(1R, 2S, 6S, 8S, 8aS)-6-methyloctahydroindolizine-1,2,8-triol] |
title_sort | 6s methyl l swainsonine 1r 2s 6s 8s 8as 6 methyloctahydroindolizine 1 2 8 triol |
work_keys_str_mv | AT hakanssona 6smethyllswainsonine1r2s6s8s8as6methyloctahydroindolizine128triol AT horneg 6smethyllswainsonine1r2s6s8s8as6methyloctahydroindolizine128triol AT fleetg 6smethyllswainsonine1r2s6s8s8as6methyloctahydroindolizine128triol AT watkind 6smethyllswainsonine1r2s6s8s8as6methyloctahydroindolizine128triol |