(6S)-Methyl-L-swainsonine [(1R, 2S, 6S, 8S, 8aS)-6-methyloctahydroindolizine-1,2,8-triol]

(6S)-Methyl-L-swainsonine, C 9H 17NO 3, together with the 6R-epimer, was formed in a synthetic sequence in which there was an ambiguity in configuration at position C-6. This ambiguity was resolved by establishing the relative s...

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Main Authors: Hakansson, A, Horne, G, Fleet, G, Watkin, D
Format: Journal article
Language:English
Published: 2007
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author Hakansson, A
Horne, G
Fleet, G
Watkin, D
author_facet Hakansson, A
Horne, G
Fleet, G
Watkin, D
author_sort Hakansson, A
collection OXFORD
description (6S)-Methyl-L-swainsonine, C 9H 17NO 3, together with the 6R-epimer, was formed in a synthetic sequence in which there was an ambiguity in configuration at position C-6. This ambiguity was resolved by establishing the relative stereochemistry of the title compound by X-ray crystallographic analysis. The absolute configuration was determined by the use of D-glycero-D-gulo-heptono-1,4-lactone as the starting material. © 2007 International Union of Crystallography. All rights reserved.
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institution University of Oxford
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spelling oxford-uuid:d771025e-ecc8-478c-8581-198d6c562cf72022-03-27T08:41:05Z(6S)-Methyl-L-swainsonine [(1R, 2S, 6S, 8S, 8aS)-6-methyloctahydroindolizine-1,2,8-triol]Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:d771025e-ecc8-478c-8581-198d6c562cf7EnglishSymplectic Elements at Oxford2007Hakansson, AHorne, GFleet, GWatkin, D(6S)-Methyl-L-swainsonine, C 9H 17NO 3, together with the 6R-epimer, was formed in a synthetic sequence in which there was an ambiguity in configuration at position C-6. This ambiguity was resolved by establishing the relative stereochemistry of the title compound by X-ray crystallographic analysis. The absolute configuration was determined by the use of D-glycero-D-gulo-heptono-1,4-lactone as the starting material. © 2007 International Union of Crystallography. All rights reserved.
spellingShingle Hakansson, A
Horne, G
Fleet, G
Watkin, D
(6S)-Methyl-L-swainsonine [(1R, 2S, 6S, 8S, 8aS)-6-methyloctahydroindolizine-1,2,8-triol]
title (6S)-Methyl-L-swainsonine [(1R, 2S, 6S, 8S, 8aS)-6-methyloctahydroindolizine-1,2,8-triol]
title_full (6S)-Methyl-L-swainsonine [(1R, 2S, 6S, 8S, 8aS)-6-methyloctahydroindolizine-1,2,8-triol]
title_fullStr (6S)-Methyl-L-swainsonine [(1R, 2S, 6S, 8S, 8aS)-6-methyloctahydroindolizine-1,2,8-triol]
title_full_unstemmed (6S)-Methyl-L-swainsonine [(1R, 2S, 6S, 8S, 8aS)-6-methyloctahydroindolizine-1,2,8-triol]
title_short (6S)-Methyl-L-swainsonine [(1R, 2S, 6S, 8S, 8aS)-6-methyloctahydroindolizine-1,2,8-triol]
title_sort 6s methyl l swainsonine 1r 2s 6s 8s 8as 6 methyloctahydroindolizine 1 2 8 triol
work_keys_str_mv AT hakanssona 6smethyllswainsonine1r2s6s8s8as6methyloctahydroindolizine128triol
AT horneg 6smethyllswainsonine1r2s6s8s8as6methyloctahydroindolizine128triol
AT fleetg 6smethyllswainsonine1r2s6s8s8as6methyloctahydroindolizine128triol
AT watkind 6smethyllswainsonine1r2s6s8s8as6methyloctahydroindolizine128triol