Doubly diastereoselective [3,3]-sigmatropic aza-Claisen rearrangements.

Doubly diastereoselective [3,3]-sigmatropic aza-Claisen rearrangements.

The doubly diastereoselective [3,3]-sigmatropic aza-Claisen rearrangement of silylketene aminals derived from 5-substituted (3S,4E,alphaR)-1-benzyloxy-3-[N-acyl-N-(alpha-methylbenzyl)amino]pent-4-enes furnishes 2,3-disubstituted (R)-N-alpha-methylbenzyl (2S,3R,4E)-7-benzyloxyhept-4-enamides in &...

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Dettagli Bibliografici
Autori principali:	Davies, S, Garner, A, Nicholson, R, Osborne, J, Roberts, P, Savory, E, Smith, A, Thomson, J
Natura:	Journal article
Lingua:	English
Pubblicazione:	2009

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