Synthesis, structure revision, and absolute configuration of (+)-didemniserinolipid B, a serinol marine natural product from a tunicate Didemnum sp.
[structure: see text] En route to proving the absolute and relative stereochemistry, through synthesis, of (+)-didemniserinolipid B (1), the first natural serinolipid isolated from a tunicate Didemnum sp., it was discovered that the isolated natural product was in fact the 31-sulfate configured 8R,9...
| Autori principali: | , , , , |
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| Natura: | Journal article |
| Lingua: | English |
| Pubblicazione: |
2002
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| _version_ | 1826299299318726656 |
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| author | Kiyota, H Dixon, D Luscombe, C Hettstedt, S Ley, S |
| author_facet | Kiyota, H Dixon, D Luscombe, C Hettstedt, S Ley, S |
| author_sort | Kiyota, H |
| collection | OXFORD |
| description | [structure: see text] En route to proving the absolute and relative stereochemistry, through synthesis, of (+)-didemniserinolipid B (1), the first natural serinolipid isolated from a tunicate Didemnum sp., it was discovered that the isolated natural product was in fact the 31-sulfate configured 8R,9R,10R,13S,30S. This structural reassignment was only possible after the development of a microwave-assisted method for the sulfation of unreactive hydroxyl groups. |
| first_indexed | 2024-03-07T04:59:48Z |
| format | Journal article |
| id | oxford-uuid:d7e4df8c-0941-4186-9dfa-e61384b8f95f |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T04:59:48Z |
| publishDate | 2002 |
| record_format | dspace |
| spelling | oxford-uuid:d7e4df8c-0941-4186-9dfa-e61384b8f95f2022-03-27T08:44:17ZSynthesis, structure revision, and absolute configuration of (+)-didemniserinolipid B, a serinol marine natural product from a tunicate Didemnum sp.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:d7e4df8c-0941-4186-9dfa-e61384b8f95fEnglishSymplectic Elements at Oxford2002Kiyota, HDixon, DLuscombe, CHettstedt, SLey, S[structure: see text] En route to proving the absolute and relative stereochemistry, through synthesis, of (+)-didemniserinolipid B (1), the first natural serinolipid isolated from a tunicate Didemnum sp., it was discovered that the isolated natural product was in fact the 31-sulfate configured 8R,9R,10R,13S,30S. This structural reassignment was only possible after the development of a microwave-assisted method for the sulfation of unreactive hydroxyl groups. |
| spellingShingle | Kiyota, H Dixon, D Luscombe, C Hettstedt, S Ley, S Synthesis, structure revision, and absolute configuration of (+)-didemniserinolipid B, a serinol marine natural product from a tunicate Didemnum sp. |
| title | Synthesis, structure revision, and absolute configuration of (+)-didemniserinolipid B, a serinol marine natural product from a tunicate Didemnum sp. |
| title_full | Synthesis, structure revision, and absolute configuration of (+)-didemniserinolipid B, a serinol marine natural product from a tunicate Didemnum sp. |
| title_fullStr | Synthesis, structure revision, and absolute configuration of (+)-didemniserinolipid B, a serinol marine natural product from a tunicate Didemnum sp. |
| title_full_unstemmed | Synthesis, structure revision, and absolute configuration of (+)-didemniserinolipid B, a serinol marine natural product from a tunicate Didemnum sp. |
| title_short | Synthesis, structure revision, and absolute configuration of (+)-didemniserinolipid B, a serinol marine natural product from a tunicate Didemnum sp. |
| title_sort | synthesis structure revision and absolute configuration of didemniserinolipid b a serinol marine natural product from a tunicate didemnum sp |
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