FREE-RADICAL REARRANGEMENT OF ALKENYL EPOXY SILANES - ISOLATION OF ALPHA-TRIMETHYLSILYL ALDEHYDES
The thiyl-radical induced fragmentation of alkenyl epoxy silanes has been found to afford α-trimethylsilyl aldehydes as the immediate products. These may be isolated, rearranged to trimethylsilyl dienol ethers, or converted to 1,3-dienes with high stereoselectivity. © 1994.
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Format: | Journal article |
Language: | English |
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1994
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_version_ | 1797097900300304384 |
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author | Robertson, J Burrows, J |
author_facet | Robertson, J Burrows, J |
author_sort | Robertson, J |
collection | OXFORD |
description | The thiyl-radical induced fragmentation of alkenyl epoxy silanes has been found to afford α-trimethylsilyl aldehydes as the immediate products. These may be isolated, rearranged to trimethylsilyl dienol ethers, or converted to 1,3-dienes with high stereoselectivity. © 1994. |
first_indexed | 2024-03-07T05:01:55Z |
format | Journal article |
id | oxford-uuid:d88b5a09-04c1-440d-89c4-5b7283548fe5 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-07T05:01:55Z |
publishDate | 1994 |
record_format | dspace |
spelling | oxford-uuid:d88b5a09-04c1-440d-89c4-5b7283548fe52022-03-27T08:49:38ZFREE-RADICAL REARRANGEMENT OF ALKENYL EPOXY SILANES - ISOLATION OF ALPHA-TRIMETHYLSILYL ALDEHYDESJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:d88b5a09-04c1-440d-89c4-5b7283548fe5EnglishSymplectic Elements at Oxford1994Robertson, JBurrows, JThe thiyl-radical induced fragmentation of alkenyl epoxy silanes has been found to afford α-trimethylsilyl aldehydes as the immediate products. These may be isolated, rearranged to trimethylsilyl dienol ethers, or converted to 1,3-dienes with high stereoselectivity. © 1994. |
spellingShingle | Robertson, J Burrows, J FREE-RADICAL REARRANGEMENT OF ALKENYL EPOXY SILANES - ISOLATION OF ALPHA-TRIMETHYLSILYL ALDEHYDES |
title | FREE-RADICAL REARRANGEMENT OF ALKENYL EPOXY SILANES - ISOLATION OF ALPHA-TRIMETHYLSILYL ALDEHYDES |
title_full | FREE-RADICAL REARRANGEMENT OF ALKENYL EPOXY SILANES - ISOLATION OF ALPHA-TRIMETHYLSILYL ALDEHYDES |
title_fullStr | FREE-RADICAL REARRANGEMENT OF ALKENYL EPOXY SILANES - ISOLATION OF ALPHA-TRIMETHYLSILYL ALDEHYDES |
title_full_unstemmed | FREE-RADICAL REARRANGEMENT OF ALKENYL EPOXY SILANES - ISOLATION OF ALPHA-TRIMETHYLSILYL ALDEHYDES |
title_short | FREE-RADICAL REARRANGEMENT OF ALKENYL EPOXY SILANES - ISOLATION OF ALPHA-TRIMETHYLSILYL ALDEHYDES |
title_sort | free radical rearrangement of alkenyl epoxy silanes isolation of alpha trimethylsilyl aldehydes |
work_keys_str_mv | AT robertsonj freeradicalrearrangementofalkenylepoxysilanesisolationofalphatrimethylsilylaldehydes AT burrowsj freeradicalrearrangementofalkenylepoxysilanesisolationofalphatrimethylsilylaldehydes |