FREE-RADICAL REARRANGEMENT OF ALKENYL EPOXY SILANES - ISOLATION OF ALPHA-TRIMETHYLSILYL ALDEHYDES
The thiyl-radical induced fragmentation of alkenyl epoxy silanes has been found to afford α-trimethylsilyl aldehydes as the immediate products. These may be isolated, rearranged to trimethylsilyl dienol ethers, or converted to 1,3-dienes with high stereoselectivity. © 1994.
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
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1994
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| _version_ | 1797097900300304384 |
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| author | Robertson, J Burrows, J |
| author_facet | Robertson, J Burrows, J |
| author_sort | Robertson, J |
| collection | OXFORD |
| description | The thiyl-radical induced fragmentation of alkenyl epoxy silanes has been found to afford α-trimethylsilyl aldehydes as the immediate products. These may be isolated, rearranged to trimethylsilyl dienol ethers, or converted to 1,3-dienes with high stereoselectivity. © 1994. |
| first_indexed | 2024-03-07T05:01:55Z |
| format | Journal article |
| id | oxford-uuid:d88b5a09-04c1-440d-89c4-5b7283548fe5 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T05:01:55Z |
| publishDate | 1994 |
| record_format | dspace |
| spelling | oxford-uuid:d88b5a09-04c1-440d-89c4-5b7283548fe52022-03-27T08:49:38ZFREE-RADICAL REARRANGEMENT OF ALKENYL EPOXY SILANES - ISOLATION OF ALPHA-TRIMETHYLSILYL ALDEHYDESJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:d88b5a09-04c1-440d-89c4-5b7283548fe5EnglishSymplectic Elements at Oxford1994Robertson, JBurrows, JThe thiyl-radical induced fragmentation of alkenyl epoxy silanes has been found to afford α-trimethylsilyl aldehydes as the immediate products. These may be isolated, rearranged to trimethylsilyl dienol ethers, or converted to 1,3-dienes with high stereoselectivity. © 1994. |
| spellingShingle | Robertson, J Burrows, J FREE-RADICAL REARRANGEMENT OF ALKENYL EPOXY SILANES - ISOLATION OF ALPHA-TRIMETHYLSILYL ALDEHYDES |
| title | FREE-RADICAL REARRANGEMENT OF ALKENYL EPOXY SILANES - ISOLATION OF ALPHA-TRIMETHYLSILYL ALDEHYDES |
| title_full | FREE-RADICAL REARRANGEMENT OF ALKENYL EPOXY SILANES - ISOLATION OF ALPHA-TRIMETHYLSILYL ALDEHYDES |
| title_fullStr | FREE-RADICAL REARRANGEMENT OF ALKENYL EPOXY SILANES - ISOLATION OF ALPHA-TRIMETHYLSILYL ALDEHYDES |
| title_full_unstemmed | FREE-RADICAL REARRANGEMENT OF ALKENYL EPOXY SILANES - ISOLATION OF ALPHA-TRIMETHYLSILYL ALDEHYDES |
| title_short | FREE-RADICAL REARRANGEMENT OF ALKENYL EPOXY SILANES - ISOLATION OF ALPHA-TRIMETHYLSILYL ALDEHYDES |
| title_sort | free radical rearrangement of alkenyl epoxy silanes isolation of alpha trimethylsilyl aldehydes |
| work_keys_str_mv | AT robertsonj freeradicalrearrangementofalkenylepoxysilanesisolationofalphatrimethylsilylaldehydes AT burrowsj freeradicalrearrangementofalkenylepoxysilanesisolationofalphatrimethylsilylaldehydes |