FREE-RADICAL REARRANGEMENT OF ALKENYL EPOXY SILANES - ISOLATION OF ALPHA-TRIMETHYLSILYL ALDEHYDES
The thiyl-radical induced fragmentation of alkenyl epoxy silanes has been found to afford α-trimethylsilyl aldehydes as the immediate products. These may be isolated, rearranged to trimethylsilyl dienol ethers, or converted to 1,3-dienes with high stereoselectivity. © 1994.
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
| Published: |
1994
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