Semi-circular potential sweep voltammetry: experimental verification and determination of the formal potential of a reversible redox couple
The use and merits of a semi-circular potential waveform in place of the conventional triangular waveform has been reported [J. Electroanal. Chem. 2018, 818, 140–148] on the basis of computational simulations. We report the experimental application of this new method to the study of the electrochemi...
| Váldodahkkit: | , , , |
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| Materiálatiipa: | Journal article |
| Almmustuhtton: |
Elsevier
2019
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| Čoahkkáigeassu: | The use and merits of a semi-circular potential waveform in place of the conventional triangular waveform has been reported [J. Electroanal. Chem. 2018, 818, 140–148] on the basis of computational simulations. We report the experimental application of this new method to the study of the electrochemically reversible [Ru(NH3)6]3+/2+ redox couple at a macroelectrode. The method is used to determine the formal potential of this redox couple. Agreement between theory and experiment is good. |
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