Semi-circular potential sweep voltammetry: experimental verification and determination of the formal potential of a reversible redox couple
The use and merits of a semi-circular potential waveform in place of the conventional triangular waveform has been reported [J. Electroanal. Chem. 2018, 818, 140–148] on the basis of computational simulations. We report the experimental application of this new method to the study of the electrochemi...
| Main Authors: | , , , |
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| Format: | Journal article |
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Elsevier
2019
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| _version_ | 1797097901493583872 |
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| author | Amin, H Uchida, Y Kätelhön, E Compton, R |
| author_facet | Amin, H Uchida, Y Kätelhön, E Compton, R |
| author_sort | Amin, H |
| collection | OXFORD |
| description | The use and merits of a semi-circular potential waveform in place of the conventional triangular waveform has been reported [J. Electroanal. Chem. 2018, 818, 140–148] on the basis of computational simulations. We report the experimental application of this new method to the study of the electrochemically reversible [Ru(NH3)6]3+/2+ redox couple at a macroelectrode. The method is used to determine the formal potential of this redox couple. Agreement between theory and experiment is good. |
| first_indexed | 2024-03-07T05:01:56Z |
| format | Journal article |
| id | oxford-uuid:d88cc394-1cc4-49a8-8319-06bb48c2ff86 |
| institution | University of Oxford |
| last_indexed | 2024-03-07T05:01:56Z |
| publishDate | 2019 |
| publisher | Elsevier |
| record_format | dspace |
| spelling | oxford-uuid:d88cc394-1cc4-49a8-8319-06bb48c2ff862022-03-27T08:49:43ZSemi-circular potential sweep voltammetry: experimental verification and determination of the formal potential of a reversible redox coupleJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:d88cc394-1cc4-49a8-8319-06bb48c2ff86Symplectic Elements at OxfordElsevier2019Amin, HUchida, YKätelhön, ECompton, RThe use and merits of a semi-circular potential waveform in place of the conventional triangular waveform has been reported [J. Electroanal. Chem. 2018, 818, 140–148] on the basis of computational simulations. We report the experimental application of this new method to the study of the electrochemically reversible [Ru(NH3)6]3+/2+ redox couple at a macroelectrode. The method is used to determine the formal potential of this redox couple. Agreement between theory and experiment is good. |
| spellingShingle | Amin, H Uchida, Y Kätelhön, E Compton, R Semi-circular potential sweep voltammetry: experimental verification and determination of the formal potential of a reversible redox couple |
| title | Semi-circular potential sweep voltammetry: experimental verification and determination of the formal potential of a reversible redox couple |
| title_full | Semi-circular potential sweep voltammetry: experimental verification and determination of the formal potential of a reversible redox couple |
| title_fullStr | Semi-circular potential sweep voltammetry: experimental verification and determination of the formal potential of a reversible redox couple |
| title_full_unstemmed | Semi-circular potential sweep voltammetry: experimental verification and determination of the formal potential of a reversible redox couple |
| title_short | Semi-circular potential sweep voltammetry: experimental verification and determination of the formal potential of a reversible redox couple |
| title_sort | semi circular potential sweep voltammetry experimental verification and determination of the formal potential of a reversible redox couple |
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